Intermolecular excimer formation in dinuclear metal complexes

被引：1

作者：

Yano, Y ^{[1
]}

Hino, K ^{[1
]}

Nakata, R ^{[1
]}

Sekiya, H ^{[1
]}

Maeda, Y ^{[1
]}

机构：

[1] Kyushu Univ, Grad Sch Sci, Dept Chem & Phys, Higashi Ku, Fukuoka 8128581, Japan

来源：

CHEMISTRY LETTERS | 1999年 / 11期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1246/cl.1999.1151

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this paper the intramolecular/intermolecular excimer formations of [Fe-2(bpmp)(1-pyace)(2)](BF4)(2) [ZnFe(bpmp)(1-pyace)(2)](ClO4)(2) and [Zn-2(bpmp)(1-pyace)(2)]ClO4 which contain 1-pyreneacetic acid as a chromophore are reported. The fluorescent properties of the ZnZn complex offer the intramolecular dimers of the two chromophores in addition to intermolecular dimers due to the intermolecular stacking. The ZnFe and FeFe complexes are under the strong influence of quenching and show weak intramolecular/intermolecular excimer formation in the concentration more than 10(-4) M. The emission intensities and intensity ratios (I-E/I-M) of the fluorescence are dependent on the metal ions.

引用

页码：1151 / 1152

页数：2

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