Preparation of Na-P1-Type Zeolite and its Composite Material with Nanosized Magnetite

被引:18
作者
Aono, Hiromichi [1 ]
Tamura, Kazumasa [1 ]
Johan, Erni [2 ]
Yamamoto, Toru [2 ]
Matsue, Naoto [2 ]
Henmi, Teruo [2 ]
机构
[1] Ehime Univ, Grad Sch Sci & Engn, Matsuyama, Ehime 7908577, Japan
[2] Ehime Univ, Fac Agr, Matsuyama, Ehime 7908566, Japan
关键词
D O I
10.1111/jace.12557
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The Na-P1-type zeolite having a high cation-exchange capacity (CEC) was obtained using the waste coal fly ash from thermal power stations and a 2M NaOH solution at 100 degrees C. The Na-P1-type zeolite was formed with the reaction time of 6h at 100 degrees C, and its CEC value increased with an increase in the reaction time. The addition of a suitable amount of NaAlO2 to the fly ash was also effective for improving the CEC value. A new composite material consisting of the Na-P1-type zeolite and magnetite was synthesized from the fly ash and iron chlorides because the magnetic collection was possible using this composite material after radioactive Cs+ ion adsorption. The existence of nanosized magnetites in the polycrystalline zeolite (several micrometers) was confirmed by TEM observations. The CEC and magnetic property of these composite materials were characterized.
引用
收藏
页码:3218 / 3222
页数:5
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