Transition-Metal-Catalyzed Cross-Coupling Reactions of Grignard Reagents

被引：28

作者：

Juhasz, Kinga ^{[1
]}

Magyar, Agnes ^{[1
]}

Hell, Zoltan ^{[1
]}

机构：

[1] Budapest Univ Technol & Econ, Dept Organ Chem & Technol, Muegyet Rkp 3, H-1111 Budapest, Hungary

来源：

SYNTHESIS-STUTTGART | 2021年 / 53卷 / 06期

关键词：

transition metals; Grignard reagent; cross-coupling; organometallic reagent; organic halides; Kumada-Tamao-Corriu coupling; SECONDARY ALKYL-HALIDES; CARBON BOND FORMATION; NICKEL-INDUCED CONVERSION; ONE-STEP TRANSFORMATIONS; AMIDO PINCER COMPLEXES; ARYL CHLORIDES; ALKENYL HALIDES; SUBSTITUTED PYRIDINES; EFFICIENT SYNTHESIS; DIRECT ARYLATION;

D O I：

10.1055/s-0040-1705986

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Transition-metal-catalyzed cross-coupling of organo-halides, ethers, sulfides, amines, and alcohols (and derivatives thereof) with Grignard reagents, known as the Kumada-Tamao-Corriu reaction, can be used to prepare important intermediates in the synthesis of numerous-biologically active compounds. The most frequently used transition metals are nickel, palladium, and iron, but there are several examples for cross-coupling reactions catalyzed by copper, cobalt, manganese, chromium, etc. salts and complexes. The aim of this review is to summarize the most important transition-metal-catalyzed cross-coupling reactions realized in the period 2000 to 2020.

引用

页码：983 / 1002

页数：20

共 179 条

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