New tri- and tetranuclear transition metal spin clusters incorporating a versatile polydentate Schiff base ligand

被引：73

作者：

Boskovic, C

Rusanov, E

Stoeckli-Evans, H

Güdel, HU

机构：

[1] Univ Bern, Dept Chem & Biochem, CH-3000 Bern 9, Switzerland

[2] Univ Neuchatel, Inst Chim, CH-2007 Neuchatel, Switzerland

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2002年 / 5卷 / 10期

关键词：

transition metal spin clusters; Schiff base ligands; trinuclear complexes; tetranuclear complexes; crystal structures;

D O I：

10.1016/S1387-7003(02)00595-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A trinuclear Fe(III) complex [Fe-3(OAc)(3)L-3] (1), a tetranuclear Mn(III) complex [Mn4Cl4L4] (2) and a tetranuclear Ni(II) complex [Ni-4(MeOH)(4)L-4] (3) have been synthesized from the reaction of simple metal salts with ligands derived from salicylidene-2ethanolamine (H2L). Structural characterization of the three complexes reveals distinctly different topologies, despite the similar coordination modes of the ligand L2-. Preliminary magnetochemical studies have been performed and reveal spin ground states of S = 1/2,8 and 4 for complexes 1, 2 and 3, respectively. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：881 / 886

页数：6