New tri- and tetranuclear transition metal spin clusters incorporating a versatile polydentate Schiff base ligand

被引：73
作者：
Boskovic, C
Rusanov, E
Stoeckli-Evans, H
Güdel, HU
机构：
[1] Univ Bern, Dept Chem & Biochem, CH-3000 Bern 9, Switzerland
[2] Univ Neuchatel, Inst Chim, CH-2007 Neuchatel, Switzerland
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2002年 / 5卷 / 10期
关键词：
transition metal spin clusters; Schiff base ligands; trinuclear complexes; tetranuclear complexes; crystal structures;
D O I：
10.1016/S1387-7003(02)00595-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A trinuclear Fe(III) complex [Fe-3(OAc)(3)L-3] (1), a tetranuclear Mn(III) complex [Mn4Cl4L4] (2) and a tetranuclear Ni(II) complex [Ni-4(MeOH)(4)L-4] (3) have been synthesized from the reaction of simple metal salts with ligands derived from salicylidene-2ethanolamine (H2L). Structural characterization of the three complexes reveals distinctly different topologies, despite the similar coordination modes of the ligand L2-. Preliminary magnetochemical studies have been performed and reveal spin ground states of S = 1/2,8 and 4 for complexes 1, 2 and 3, respectively. (C) 2002 Elsevier Science B.V. All rights reserved.
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收藏
页码：881 / 886
页数：6
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