Kinetics of oxidation of fullerene C60 with dimethyldioxirane

被引：2

作者：

Antipin, AV ^{[1
]}

Shishlov, NM ^{[1
]}

Grabovskii, SA ^{[1
]}

Kabal'nova, NN ^{[1
]}

机构：

[1] Russian Acad Sci, Ufa Res Ctr, Inst Organ Chem, Ufa 450054, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2004年 / 53卷 / 04期

关键词：

dimethyldioxirane; fullerene; kinetics; oxidation; free radicals;

D O I：

10.1023/B:RUCB.0000037845.82051.50

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The kinetics of the reaction of dimethyldioxirane with fullerene C-60 was studied, and the activation parameters logk = (8.3+/-0.8) - (14.2+/-0.9)/theta, (theta = 2.3RT kcal mol(-1)) (20-45 degreesC) were determined. The formation of paramagnetic particles was detected.

引用

页码：800 / 802

页数：3

共 10 条

[1] SPECTRAL AND CHEMICAL-PROPERTIES OF DIMETHYLDIOXIRANE AS DETERMINED BY EXPERIMENT AND ABINITIO CALCULATIONS [J].

ADAM, W ;

CHAN, YY ;

CREMER, D ;

GAUSS, J ;

SCHEUTZOW, D ;

SCHINDLER, M .

JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (13) :2800-2803

[2] Decomposition modes of dioxirane, methyldioxirane and dimethyldioxirane - a CCSD(T), MR-AQCC and DFT investigation [J].

Cremer, D ;

Kraka, E ;

Szalay, PG .

CHEMICAL PHYSICS LETTERS, 1998, 292 (1-2) :97-109

[3] Covalent fullerene chemistry [J].

Diederich, F ;

Thilgen, C .

SCIENCE, 1996, 271 (5247) :317-323

[4] REACTION OF C-60 WITH DIMETHYLDIOXIRANE - FORMATION OF AN EPOXIDE AND A 1,3-DIOXOLANE DERIVATIVE [J].

ELEMES, Y ;

SILVERMAN, SK ;

SHEU, CM ;

KAO, M ;

FOOTE, CS ;

ALVAREZ, MM ;

WHETTEN, RL .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (03) :351-353

[5] Oxyfunctionalization of non-natural targets by dioxiranes.: 3.: Efficient oxidation of buckminsterfullerene C60 with methyl (trifluoromethyl) dioxirane [J].

Fusco, C ;

Seraglia, R ;

Curci, R ;

Lucchini, V .

JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (22) :8363-8368

[6] Availability and reactivity of concentrated dimethyldioxirane solutions in solvents other than acetone [J].

Gibert, M ;

Ferrer, M ;

SanchezBaeza, F ;

Messeguer, A .

TETRAHEDRON, 1997, 53 (25) :8643-8650

[7] The kinetic regularities, products, and mechanism of the thermal decomposition of dimethyldioxirane. The contribution of molecular and radical reaction channels [J].

Khursan, SL ;

Grabovskii, SA ;

Kabal'nova, NN ;

Galkin, EG ;

Shereshovets, VV .

RUSSIAN CHEMICAL BULLETIN, 2000, 49 (08) :1338-1348

[8] OXIDATIONS BY METHYL(TRIFLUOROMETHYL)DIOXIRANE .4. OXYFUNCTIONALIZATION OF AROMATIC-HYDROCARBONS [J].

MELLO, R ;

CIMINALE, F ;

FIORENTINO, M ;

FUSCO, C ;

PRENCIPE, T ;

CURCI, R .

TETRAHEDRON LETTERS, 1990, 31 (42) :6097-6100

[9] DIOXIRANES - SYNTHESIS AND REACTIONS OF METHYLDIOXIRANES [J].

MURRAY, RW ;

JEYARAMAN, R .

JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (16) :2847-2853

[10] Discrete fulleride anions and fullerenium cations [J].

Reed, CA ;

Bolskar, RD .

CHEMICAL REVIEWS, 2000, 100 (03) :1075-1119

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