Exo-selective asymmetric Diels-Alder reaction of acrylate ester

被引：17

作者：

Kawamura, M ^{[1
]}

Kudo, K ^{[1
]}

机构：

[1] Univ Tokyo, Inst Ind Sci, Meguro Ku, Tokyo 1538505, Japan

来源：

CHIRALITY | 2002年 / 14卷 / 09期

关键词：

binaphthyl; chiral auxiliary; exo-selective Diels-Alder reaction;

D O I：

10.1002/chir.10130

中图分类号：

R914 [药物化学];

学科分类号：

100701 ;

摘要：

Diels-Alder reaction of 2-acryloyloxy-2'-(2-pyridylazo)-1,1'-binaphthyl with cyclopentadiene in the presence of an equimolar amount of tin (IV) chloride showed unusual exo-selectivity with a high degree of diastereofacial differentiation. (C) 2002 Wiley-Liss, Inc.

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页码：727 / 730

页数：4

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