Synthesis and structure of 1-D heterometallic thiocyanato-bridged CuIIGdIII polymers with ferromagnetic properties

被引:59
作者
Novitchi, G
Costes, JP
Donnadieu, B
机构
[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse, France
[2] Moldova State Univ, Dept Chem, Kishinev 2009, Moldova
关键词
heterometallic complexes; copper; lanthanides; magnetic properties;
D O I
10.1002/ejic.200300957
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Reaction of the tetracoordinate CuLA and CuLB complexes with Gd(NCS)(3) leads to two unique one-dimensional {Cu-Gd}(n) thiocyanato-bridged (1) and hydrogen-bonded (11) polymers, depending on the periphery of the L-A and L-B ligands, with ferromagnetic properties. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004).
引用
收藏
页码:1808 / 1812
页数:5
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