A Mixed-Cluster Approach for Building a Highly Porous Cobalt(II) Isonicotinic Acid Framework: Gas Sorption Properties and Computational Analyses

被引：30

作者：

Chen, Di-Ming ^{[1
]}

Zhang, Nan-Nan ^{[1
]}

Liu, Chun-Sen ^{[1
]}

Jiang, Zhi-Hao ^{[1
]}

Wang, Xing-Dong ^{[1
]}

Du, Miao ^{[1
]}

机构：

[1] Zhengzhou Univ Light Ind, Henan Prov Key Lab Surface & Interface Sci, Zhengzhou 450002, Peoples R China

来源：

INORGANIC CHEMISTRY | 2017年 / 56卷 / 05期

基金：

中国国家自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORK; CO-II; COORDINATION FRAMEWORKS; SELECTIVE SORPTION; HYDROGEN STORAGE; H-2; SEPARATION; CRYSTAL; CAPTURE; LINKER;

D O I：

10.1021/acs.inorgchem.6b03170

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A unique channel-type metal-organic framework (MOF) built up from mixed square-planar Co-4(mu(2)-OH)(4)(mu(4)-OH) and cuboidal Co-4(mu(3)-OH)(4) clusters with an isonicotinic acid ligand has been successfully fabricated that demonstrates the highest specific surface area and high H-2 uptake capacities among all of the cobalt(II) isonicotinic acid frameworks reported so far.

引用

页码：2379 / 2382

页数：4

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