A possible role for surface carbon during ethylene epoxidation over silver catalysts

被引：9

作者：

Bradford, MCJ ^{[1
]}

Fuentes, DX ^{[1
]}

机构：

[1] CeraMem Corp, Waltham, MA 02453 USA

来源：

CATALYSIS COMMUNICATIONS | 2002年 / 3卷 / 02期

基金：

美国国家科学基金会;

关键词：

silver; ethylene epoxidation; reconstruction; carbon;

D O I：

10.1016/S1566-7367(02)00049-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Evidence obtained during an investigation of ethylene epoxidation over unsupported silver powder and Ag-Cs/alpha-Al2O3 is used to present the hypothesis that some surface sites responsible for epoxidation may deactivate under some (but not all) experimental conditions as a consequence of surface carbon deposition and/or mild surface reconstruction facilitated by surface carbon. (C) 2002 Published by Elsevier Science B.V.

引用

页码：51 / 60

页数：10

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