Direct Assembly of 2-Oxazolidinones by Chemical Fixation of Carbon Dioxide

被引：22

作者：

Niemi, Teemu ^{[1
]}

Perea-Buceta, Jesus E. ^{[1
]}

Fernandez, Israel ^{[2
]}

Alakurtti, Sami ^{[3
]}

Rantala, Erika ^{[3
]}

Repo, Timo ^{[1
]}

机构：

[1] Univ Helsinki, Dept Chem, Inorgan Chem Lab, Helsinki 00014, Finland

[2] Univ Complutense Madrid, Fac Ciencias Quim, Dept Quim Organ 1, E-28040 Madrid, Spain

[3] VTT Tech Res Ctr Finland, FI-02044 Espoo, Finland

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2014年 / 20卷 / 29期

基金：

芬兰科学院;

关键词：

2-oxazolidones; antibiotics; carbon dioxide activation; carbon dioxide fixation; density functional calculations; SELECTIVE SYNTHESIS; 1,2-AMINO ALCOHOLS; HIGHLY EFFICIENT; CYCLIC UREAS; AZIRIDINES; OXAZOLIDINONES; CYCLOADDITION; CATALYST; CO2;

D O I：

10.1002/chem.201402368

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of beta- and gamma-haloamines with carbon dioxide to give pharmaceutically relevant 2-oxazolidinones and 1,3-dioxazin-2-ones, was found to proceed efficiently in the presence of a base and in the absence of catalyst. After optimization of reaction conditions, the system was successfully expanded to a variety of haloamines, even at multigram scale. The reaction was further studied in silico by DFT calculations.

引用

页码：8867 / 8871

页数：5

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