A new acentric heterometallic inorganic-organic hybrid framework with an unusual {Cd3Na4}n array: NLO and ferroelectric properties

被引：5
|
作者：
Du, Fenglei [1 ,2 ]
Zhao, Minglei [3 ]
Long, Xifa [1 ]
Du, Shaowu [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
[3] Shandong Univ, Sch Phys, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 38卷
基金：
中国国家自然科学基金;
关键词：
Inorganic-organic hybrid material; Acentric framework; NLO; Ferroelectric property; ADSORPTION;
D O I：
10.1016/j.inoche.2013.10.011
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
By employing 1,1'-biphenyl-3,3'-dicarboxylic acid (3,3'-H(2)BPDA) as a bridging ligand, a novel acentric heterometallic inorganic-organic hybrid framework [Cd3Na4(3,3'-BPDA)(5)(DME)(7)]center dot DME (1) has been synthesized. Single crystal X-ray diffraction study reveals that 1 contains an unusual 10 {Cd3Na4}(n) motif which is further extended into a 2-fold interpenetrating layer by trans-coordinated 3,3'-BPDA(2-) ligands. Compound 1 is NLO active with a SHG effect being 0.5 times that of KDP. Besides, it also displays a potential ferroelectric property. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：39 / 42
页数：4
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