Linear and Nonlinear Optical Properties of meso-Tetra(4-ferrocenylcarbonyloxyphenyl)porphyrin and Its Zinc(II) Complex

被引：1
作者：
Zhao, Haiying [1 ]
Gu, Xuesong [1 ]
Yan, Xiaoqing [2 ,3 ]
Liu, Zhibo [2 ,3 ]
Chen, Qiang [1 ]
Bian, Zhanxi [1 ]
机构：
[1] Inner Mongolia Univ, Coll Chem & Chem Engn, Hohhot 010021, Peoples R China
[2] Nankai Univ, Minist Educ, Key Lab Weak Light Nonlinear Photon, Tianjin 300457, Peoples R China
[3] Nankai Univ, Teda Appl Phys Sch, Tianjin 300457, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 34卷 / 02期
基金：
中国国家自然科学基金;
关键词：
ferrocene; porphyrin; spectral property; Z-scan; ABSORPTION PROPERTIES; CRYSTAL-STRUCTURES; PORPHYRIN; ELECTROCHEMISTRY; FULLERENE; BEHAVIOR; PYRENE; TRIADS;
D O I：
10.6023/cjoc201308036
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
meso-Tetra(4-ferrocenylcarbonyloxyphenyl)porphyrin and its zinc(II) complex were synthesized. Their linear and nonlinear optical properties were investigated using UV-Vis absorption spectra, steady state and time-resOlved fluorescence spectra and open-aperture Z-scan measurements. The results indicated that the introduction of ferrocene to porphyrin had not affected the absorption spectra of porphyrin, but quenched the fluorescence intensively and shortened the fluorescence life-times of porphyrin, which indicated that there was almost no interaction between porphyrin and ferrocene in the ground state, but a strong interaction in the excited state. The reverse saturable absorptions of meso-tetra(4-ferrocenylcarbonyloxyphenyl)porphyrin and its zinc(II) complex were weaker than those of the corresponding meso-tetra(4-benzoyloxyphenyl)porphyrin and its zinc(II) complex, but were stronger than that of fullerene C-60 with excellent performance.
引用
收藏
页码：371 / 375
页数：5
相关论文
共 26 条
[1]   Designs, Synthesis, Characterization and Direct Electrochemistry of Zinc-Porphyrin Bearing Pyrene Noncovalent Functionalized Graphene Oxide Sheet [J].
Bi Chun ;
Li Yongjie ;
Chen Haowen ;
Yin Gui ;
Zhu Junjie .
CHINESE JOURNAL OF CHEMISTRY, 2012, 30 (08) :1722-1728
[2]   Supramolecular triads formed by axial coordination of fullerene to covalently linked zinc porphyrin-ferrocene(s): Design, syntheses, electrochemistry, and photochemistry [J].
D'Souza, F ;
Smith, PM ;
Gadde, S ;
McCarty, AL ;
Kullman, MJ ;
Zandler, ME ;
Itou, M ;
Araki, Y ;
Ito, O .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (31) :11333-11343
[3]   Synthesis and NLO behavior of Oligo(phenylenevinylene)-Porphyrin Dendrimers [J].
Flores-Rojas, Guadalupe G. ;
Lijanova, Irina V. ;
Morales-Saavedra, Omar G. ;
Sanchez-Montes, Karla ;
Martinez-Garcia, Marcos .
DYES AND PIGMENTS, 2013, 96 (01) :125-129
[4]   Photofunctional nanomaterials composed of multiporphyrins and carbon-based π-electron acceptors [J].
Fukuzumi, Shunichi ;
Kojima, Takahiko .
JOURNAL OF MATERIALS CHEMISTRY, 2008, 18 (13) :1427-1439
[5]   Optically induced switch of the surface work function in TiO2/porphyrin-C60 dyad system [J].
Fungo, Fernando ;
Milanesio, Maria E. ;
Durantini, Edgardo N. ;
Otero, Luis ;
Dittrich, Thomas .
JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (20) :2107-2112
[6]   Effect of interaction with micelles on the excited-state optical properties of zinc porphyrins and J-aggregates formation [J].
Goncalves, P. J. ;
Correa, D. S. ;
Franzen, P. L. ;
De Boni, L. ;
Almeida, L. M. ;
Mendonca, C. R. ;
Borissevitch, I. E. ;
Zilio, S. C. .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2013, 112 :309-317
[7]   Photooxygenation catalysis with a polyol-decorated disc-shaped porphyrin sensitizer:: Shell-recognition effects [J].
Griesbeck, Axel G. ;
Schaefer, Mathias ;
Uhlig, Johannes .
ADVANCED SYNTHESIS & CATALYSIS, 2008, 350 (13) :2104-2108
[8]   Ordered Nanosphere Alignment of Porphyrin for the Improvement of Nonlinear Optical Properties [J].
Huang, Changshui ;
Li, Yuliang ;
Song, Yinglin ;
Li, Yongjun ;
Liu, Huibiao ;
Zhu, Daoben .
ADVANCED MATERIALS, 2010, 22 (32) :3532-+
[9]   Modulating charge separation and charge recombination dynamics in porphyrin fullerene linked dyads and triads: Marcus-normal versus inverted region [J].
Imahori, H ;
Tamaki, K ;
Guldi, DM ;
Luo, CP ;
Fujitsuka, M ;
Ito, O ;
Sakata, Y ;
Fukuzumi, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (11) :2607-2617
[10]   Synthesis of meso-azulenylporphyrins [J].
Kurotobi, K ;
Osuka, A .
ORGANIC LETTERS, 2005, 7 (06) :1055-1058
123