Self-Diffusion in Molecular Fluids and Noble Gases: Available Data

被引:66
作者
Suarez-Iglesias, Octavio [1 ]
Medina, Ignacio [1 ]
de los Angeles Sanz, Maria [1 ]
Pizarro, Consuelo [1 ]
Bueno, Julio L. [1 ]
机构
[1] Univ Oviedo, Dept Ingn Quim & TMA, Oviedo 33071, Spain
关键词
NUCLEAR-MAGNETIC-RESONANCE; SPIN-LATTICE-RELAXATION; ROTATIONAL CORRELATION TIMES; STUDYING TRANSLATIONAL DIFFUSION; CONTROLLED PROTON RELAXATION; POTASSIUM-CHLORIDE SOLUTIONS; COMPLEX HYDROGENOUS LIQUIDS; ELASTIC NEUTRON-SCATTERING; DYNAMICAL DIMER STRUCTURE; FRAGILE GLASS-FORMER;
D O I
10.1021/acs.jced.5b00323
中图分类号
O414.1 [热力学];
学科分类号
摘要
Experimental self-diffusivities of gases, vapors, and liquids obtained by means of tracer techniques and nuclear magnetic resonance are reviewed. The considered substances range from noble gases and simple diatomics (nitrogen, oxygen, carbon monoxide, etc.) to complex organic molecules, such as phenolphthalein dimethyl ether and 2(alpha-methylbenzylamino)-5-nitropyridine, although polymers have not been included. Some comments on the applicability of neutron scattering to the determination of self-diffusion coefficients are also made. All the experimental results of the investigated systems are given as Supporting Information, whereas the references, temperatures, and pressures of these data and the main features of the measurement methods are compiled and classified.
引用
收藏
页码:2757 / 2817
页数:61
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