Cobaltaelectro-Catalyzed C-H Activation with Carbon Monoxide or Isocyanides

被引：73

作者：

Sau, Samaresh Chandra ^{[1
]}

Mei, Ruhuai ^{[1
]}

Struwe, Julia ^{[1
]}

Ackermann, Lutz ^{[1
]}

机构：

[1] Georg August Univ Gottingen, Inst Organ & Biomol Chem, Tammannstr 2, D-37077 Gottingen, Germany

来源：

CHEMSUSCHEM | 2019年 / 12卷 / 13期

关键词：

carbon monoxide; C-H activation; cobalt catalysis; electrochemistry; isocyanides; OXIDATIVE CARBONYLATION; REGIOSELECTIVE CARBONYLATION; ORGANIC ELECTROSYNTHESIS; MULTICOMPONENT REACTIONS; BOND FUNCTIONALIZATION; ALPHA-ISOCYANOACETATES; C(SP(3))-H BONDS; COBALT CATALYSIS; GREEN CHEMISTRY; CONSTRUCTION;

D O I：

10.1002/cssc.201900378

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrochemical oxidative C-H/N-H activations with isocyanides have been realized with a versatile cobalt catalyst. The widely applicable cobalt catalysis manifold further enabled electrooxidative C-H/N-H carbonylations with carbon monoxide under ambient conditions. The C-H functionalizations were efficiently realized with ample scope and outstanding functional group tolerance in a user-friendly undivided cell setup.

引用

页码：3023 / 3027

页数：5

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