A colorimetric and ratiometric fluorescent probe for sulfite based on an intramolecular cleavage mechanism

被引：32

作者：

Hou, Peng ^{[1
]}

Chen, Song ^{[1
]}

Voitchovsky, Kislon ^{[1
]}

Song, Xiangzhi ^{[1
,2
,3
]}

机构：

[1] Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China

[2] Minist Educ, Key Lab Resource Chem Nonferrous Met, Beijing, Peoples R China

[3] State Key Lab Powder Met, Changsha, Hunan, Peoples R China

来源：

LUMINESCENCE | 2014年 / 29卷 / 07期

关键词：

colorimetric; fluorescent probe; sulfite; SULFUR-DIOXIDE; BISULFITE; SENSOR; ACID; SO2;

D O I：

10.1002/bio.2616

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A colorimetric and ratiometric fluorescent sulfite probe, the levulinate of 4-hydroxynaphthalimide, was successfully synthesized from 4-hydroxy-naphthalimide and levulinic acid. Through sulfite-mediated intramolecular cleavage, the probe was converted into 4-hydroxynaphthalimide, which when excited at 450 nm, displayed a large Stokes shift due to the intramolecular charge transfer process. The probe exhibited high selectivity and sensitivity towards sulfite over other typical anionic species (F-, Cl-, Br-, I-, HPO42-, SO42 -, NO3-, AcO-, ClO4-, HCO3-) in HEPES-buffered solution (25 mM, pH 7.4, 50% acetonitrile, v/v). Copyright (C) 2013 John Wiley & Sons, Ltd.

引用

页码：749 / 753

页数：5

共 29 条

[1] Determination of SO2 in wines using a flow injection analysis system with potentiometric detection [J].

Araújo, AN ;

Couto, CMCM ;

Lima, JLFC ;

Montenegro, MCBSM .

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1998, 46 (01) :168-172

[2] Determination of sulfur dioxide and ascorbic acid in beverages using a dual channel flow injection electrochemical detection system [J].

Cardwell, TJ ;

Christophersen, MJ .

ANALYTICA CHIMICA ACTA, 2000, 416 (01) :105-110

[3] A colorimetric and ratiometric fluorescent probe for Cu2+ with a large red shift and its imaging in living cells [J].

Chen, Song ;

Hou, Peng ;

Foley, James W. ;

Song, Xiangzhi .

RSC ADVANCES, 2013, 3 (16) :5591-5596

[4] A highly sulfite-selective ratiometric fluorescent probe based on ESIPT [J].

Chen, Song ;

Hou, Peng ;

Wang, Jianxiu ;

Song, Xiangzhi .

RSC ADVANCES, 2012, 2 (29) :10869-10873

[5] A Ratiometric Fluorescent Probe for Rapid Detection of Hydrogen Sulfide in Mitochondria [J].

Chen, Yuncong ;

Zhu, Chengcheng ;

Yang, Zhenghao ;

Chen, Junjie ;

He, Yafeng ;

Jiao, Yang ;

He, Weijiang ;

Qiu, Lin ;

Cen, Jiajie ;

Guo, Zijian .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (06) :1688-1691

[6] Chromogenic and Fluorogenic Signaling of Sulfite by Selective Deprotection of Resorufin Levulinate [J].

Choi, Myung Gil ;

Hwang, Jiyoung ;

Eor, Suyoung ;

Chang, Suk-Kyu .

ORGANIC LETTERS, 2010, 12 (24) :5624-5627

[7]

Ensafi AA, 2010, INT J ELECTROCHEM SC, V5, P392

[8] A Boron-dipyrromethene-Based Fluorescent Probe for Colorimetric and Ratiometric Detection of Sulfite [J].

Gu, Xianfeng ;

Liu, Chunhua ;

Zhu, Yi-Chun ;

Zhu, Yi-Zhun .

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2011, 59 (22) :11935-11939

[9] Chemiluminescence of sulfite based on auto-oxidation sensitized by rhodamine 6G [J].

Huang, YM ;

Zhang, C ;

Zhang, XR ;

Zhang, ZJ .

ANALYTICA CHIMICA ACTA, 1999, 391 (01) :95-100

[10] A sensitive colorimetric and ratiometric fluorescent probe for mercury species in aqueous solution and living cells [J].

Jiang, Jie ;

Liu, Wei ;

Cheng, Ju ;

Yang, Lizi ;

Jiang, Huie ;

Bai, Decheng ;

Liu, Weisheng .

CHEMICAL COMMUNICATIONS, 2012, 48 (67) :8371-8373

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