Alkali Metal Reduction of 1,2-Bis[(2,6-dibenzhydryl-4-methylphenyl)imino]acenaphthene (ArBIG-bian) to Radical-Anion

被引：9
作者：
Moskalev, Mikhail V. [1 ]
Razborov, Danila A. [1 ]
Skatova, Alexandra A. [1 ]
Bazanov, Andrey A. [1 ]
Fedushkin, Igor L. [1 ]
机构：
[1] Russian Acad Sci, GA Razuvaev Inst Organometall Chem, Tropinina Str 49, Nizhnii Novgorod 603137, Russia
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2021年 / 2021卷 / 05期
基金：
俄罗斯基础研究基金会;
关键词：
Alkali metals; Bulky ligands; Acenaphthene-1; 2-diimines; ESR spectroscopy; Structure elucidation; ALPHA-DIIMINE NICKEL; INSERTION POLYMERIZATION; CRYSTAL-STRUCTURES; GALLIUM COMPLEXES; CATALYTIC HYDROSILYLATION; ELECTRONIC COMMUNICATION; MOLECULAR-STRUCTURES; MONOMERIC MAGNESIUM; CALCIUM COMPLEXES; SOLUTION BEHAVIOR;
D O I：
10.1002/ejic.202000909
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reduction of Ar-BIG-bian (1, 1,2-bis[(2,6-dibenzhydryl-4-methylphenyl)imino]acenaphthene) with one molar equivalent of Li, Na or K in tetrahydrofuran (THF) affords corresponding radical-anionic salts (Ar-BIG-bian)M(THF) (M=Li, 2; Na, 3; K, 4). Compounds 2-4 were isolated in good yields and characterized by the elemental analysis, IR and ESR spectroscopy as well as the single-crystal X-Ray analysis. Bulky Ph-2(H)C groups in Ar-BIG-bian ligand prevent dimerization of complexes 2-4 and limit a number of coordinated THF molecules to one. In all three products a saturation of the alkali metal coordination sphere is achieved through an interaction with Ph rings of Ph-2(H)C substituents.
引用
收藏
页码：458 / 463
页数：6
相关论文
共 125 条
  • [91] Mononuclear gallium complexes with the redox-active dmp-bian ligand (dmp-bian is 1,2-bis[(2,6-dimethylphenyl)imino]acenaphthene): synthesis and reactions with alkynes
    Skatova, A. A.
    Bazyakina, N. L.
    Fedushkin, I. L.
    Piskunov, A., V
    Druzhkov, N. O.
    Cherkasov, A., V
    [J]. RUSSIAN CHEMICAL BULLETIN, 2019, 68 (02) : 275 - 283
  • [92] EasySpin, a comprehensive software package for spectral simulation and analysis in EPR
    Stoll, S
    Schweiger, A
    [J]. JOURNAL OF MAGNETIC RESONANCE, 2006, 178 (01) : 42 - 55
  • [93] Aryl-substituted BIAN complexes of iron dibromide: Synthesis, X-ray and electronic structure, and catalytic hydrosilylation activity
    Supej, Michael J.
    Volkov, Alexander
    Darko, Louisa
    West, Ryan A.
    Darmon, Jonathan M.
    Schulz, Charles E.
    Wheeler, Kraig A.
    Hoyt, Helen M.
    [J]. POLYHEDRON, 2016, 114 : 403 - 414
  • [94] Synthesis of polycyclic polyolefins by a Pd-catalyzed isomerization polymerization of vinylcycloalkanes
    Takeuchi, Daisuke
    Nakamura, Karin
    Tokura, Yuki
    Tsubamoto, Ryuji
    Osakada, Kohtaro
    [J]. POLYMER JOURNAL, 2020, 52 (01) : 93 - 101
  • [95] Iron catalysed selective reduction of esters to alcohols
    Tamang, Sem Raj
    Cozzolino, Anthony F.
    Findlater, Michael
    [J]. ORGANIC & BIOMOLECULAR CHEMISTRY, 2019, 17 (07) : 1834 - 1838
  • [96] Cationic para-benzhydryl substituted α-diimine nickel catalyzed ethylene and 1-decene polymerizations via controllable chain-walking
    Tian, Susu
    Zhang, Yang
    Li, Ruiping
    Wang, Fuzhou
    Li, Weimin
    [J]. INORGANICA CHIMICA ACTA, 2019, 486 : 492 - 498
  • [97] van Laren MW, 1999, ANGEW CHEM INT EDIT, V38, P3715, DOI 10.1002/(SICI)1521-3773(19991216)38:24<3715::AID-ANIE3715>3.3.CO
  • [98] 2-F
  • [99] Vasudevan K. V., 2009, ANGEW CHEM, V121, P8519
  • [100] Synthesis and structures of 1,2-bis(imino)acenaphthene (BIAN) lanthanide complexes that involve the transfer of zero, one, or two electrons
    Vasudevan, Kalyan
    Cowley, Alan H.
    [J]. CHEMICAL COMMUNICATIONS, 2007, (33) : 3464 - 3466
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