Sugar acetates as novel, renewable CO2-philes

被引:197
作者
Raveendran, P
Wallen, SL
机构
[1] Univ N Carolina, Dept Chem, Kenan Lab, Chapel Hill, NC 27599 USA
[2] Univ N Carolina, Dept Chem, Venable Labs, Chapel Hill, NC 27599 USA
关键词
D O I
10.1021/ja025508b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Acetylation of carbohydrates is proposed as a method for the synthesis of inexpensive CO2-philes that can easily be modified for a wide variety of green chemistry applications in liquid and supercritical CO2. The deliquescence of peracetylated sugars in contact with CO2 is reported in this communication as well as the unparalleled solubility of these compounds in supercritical CO2. Copyright © 2002 American Chemical Society.
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页码:7274 / 7275
页数:2
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