The mineralogy and geochemistry of the Wicheeda Carbonatite Complex, British Columbia, Canada

被引:13
作者
Dalsin, M. L. [1 ]
Groat, L. A. [1 ]
Creighton, S. [2 ]
Evans, R. J. [1 ]
机构
[1] Univ British Columbia, Dept Earth & Ocean Sci, Vancouver, BC V6T 1Z4, Canada
[2] Saskatchewan Res Council, Adv Microanal Ctr, Saskatoon, SK S7K 0X8, Canada
关键词
Carbonatites; Rare earth elements; REE-minerals; British Columbia; REE FLUORCARBONATE MINERALS; TH-PB GEOCHRONOLOGY; META-ALKALINE ROCKS; ATOMIC ARRANGEMENT; INNER-MONGOLIA; KOLA-PENINSULA; NORTH CHINA; BAYAN-OBO; SYNCHYSITE-(CE); PARISITE-(CE);
D O I
10.1016/j.oregeorev.2014.02.013
中图分类号
P5 [地质学];
学科分类号
0709 ; 081803 ;
摘要
The Wicheeda Carbonatite Complex, located 80 km northeast of Prince George in British Columbia, Canada, has been historically explored for its REE potential but, until recently, there has been very little extensive exploration or scientific study. The Complex consists of a carbonatite plug with a series of carbonatite and potassic-syenite dykes and sills emplaced into the upper Cambrian and lower Ordovician Kechika Group. The carbonatite is classified as a calcio- to ferro-carbonatite. Sodic-fenitization is common around the carbonatite and the degree of alteration and frequency of syenite occurrences increase away from the carbonatite plug. The rare earth mineralogy of the Wicheeda carbonatite was defined through the use of petrography, scanning electron microscopy, electron probe microanalysis, and single-crystal X-ray diffraction. The REE mineralogy is complex, with multiple stages of primary, late-stage, rapidly cooling crystallization. The mineralogy consists of Ca-REE-fluorocarbonates [including bastnasite-(Ce), parisite-(Ce), and synchysite-(Ce)], Ba-REE-fluorocarbonates [including cordylite-(Ce), kukharenkoite-(Ce), cebaite-(Ce), huangnoite-(Ce), and qaqarssukite-(Ce)], ancylite-(Ce), monazite-(Ce), euxenite-(Y) and allanite-(Ce); the majority of which are LREE-rich. The REE minerals typically form in anhedral aggregates with strontianite, calcite, dolomite, and ankerite. The aggregates range in size from a 1-2 mm but have been observed up to 7 cm. The Ca-REE-fluorocarbonate minerals generally form as syntaxial intergrowths whereas the other REE minerals form individual crystals. The REE content varies throughout the carbonatite intervals with an average of 9663 ppm. Evidence from the Wicheeda Carbonatite Complex and comparisons with other worldwide carbonatites suggest that the complex is derived from low-degree partial melts extracted from metasomatized lithospheric mantle. (C) 2014 Elsevier B.V. All rights reserved.
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页码:523 / 542
页数:20
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