Terpyridine complexes of first row transition metals and electrochemical reduction of CO2 to CO

被引：158

作者：

Elgrishi, Noemie ^{[1
]}

Chambers, Matthew B. ^{[1
]}

Artero, Vincent ^{[2
]}

Fontecave, Marc ^{[1
]}

机构：

[1] Univ Paris 06, UMR 8229, CNRS, Lab Chim Proc Biol,Coll France, F-75231 Paris 05, France

[2] Univ Grenoble Alpes, CNRS UMR 5249, CEA, Lab Chim & Biol Met, F-38054 Grenoble 9, France

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2014年 / 16卷 / 27期

关键词：

CARBON-DIOXIDE; ELECTROCATALYTIC REDUCTION; VISIBLE-LIGHT; ELECTROPOLYMERIZED FILMS; HOMOGENEOUS CATALYSIS; MOLECULAR CATALYSIS; WATER; HYDROGEN; OXIDATION; 2,2-BIPYRIDINE;

D O I：

10.1039/c4cp00451e

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Homoleptic terpyridine complexes of first row transition metals are evaluated as catalysts for the electrocatalytic reduction of CO2. Ni and Co-based catalytic systems are shown to reduce CO2 to CO under the conditions tested. The Ni complex was found to exhibit selectivity for CO2 over proton reduction while the Co-based system generates mixtures of CO and H-2 with CO:H-2 ratios being tuneable through variation of the applied potential.

引用

页码：13635 / 13644

页数：10

共 65 条

[1] MECHANISM AND KINETIC CHARACTERISTICS OF THE ELECTROCHEMICAL REDUCTION OF CARBON-DIOXIDE IN MEDIA OF LOW PROTON AVAILABILITY
AMATORE, C
SAVEANT, JM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (17) : 5021 - 5023
[2] Catalysis research of relevance to carbon management: Progress, challenges, and opportunities
Arakawa, H
Aresta, M
Armor, JN
Barteau, MA
Beckman, EJ
Bell, AT
Bercaw, JE
Creutz, C
Dinjus, E
Dixon, DA
Domen, K
DuBois, DL
Eckert, J
Fujita, E
Gibson, DH
Goddard, WA
Goodman, DW
Keller, J
Kubas, GJ
Kung, HH
Lyons, JE
Manzer, LE
Marks, TJ
Morokuma, K
Nicholas, KM
Periana, R
Que, L
Rostrup-Nielson, J
Sachtler, WMH
Schmidt, LD
Sen, A
Somorjai, GA
Stair, PC
Stults, BR
Tumas, W
[J]. CHEMICAL REVIEWS, 2001, 101 (04) : 953 - 996
[3] ELECTROCATALYTIC REDUCTION OF CARBON-DIOXIDE WITH IRON, COBALT, AND NICKEL-COMPLEXES OF TERDENTATE LIGANDS
ARANA, C
YAN, S
KESHAVARZK, M
POTTS, KT
ABRUNA, HD
[J]. INORGANIC CHEMISTRY, 1992, 31 (17) : 3680 - 3682
[4] ELECTROCATALYTIC REDUCTION OF CO2 AND O-2 WITH ELECTROPOLYMERIZED FILMS OF VINYL-TERPYRIDINE COMPLEXES OF FE, NI AND CO
ARANA, C
KESHAVARZ, M
POTTS, KT
ABRUNA, HD
[J]. INORGANICA CHIMICA ACTA, 1994, 225 (1-2) : 285 - 295
[5] Splitting Water with Cobalt
Artero, Vincent
Chavarot-Kerlidou, Murielle
Fontecave, Marc
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (32) : 7238 - 7266
[6] Electrocatalytic and homogeneous approaches to conversion of CO2 to liquid fuels
Benson, Eric E.
Kubiak, Clifford P.
Sathrum, Aaron J.
Smieja, Jonathan M.
[J]. CHEMICAL SOCIETY REVIEWS, 2009, 38 (01) : 89 - 99
[7] ACTIVATION OF DIOXYGEN BY CUI COMPLEXES CONTAINING 2,2'-BIPYRIDINE OR 1,10-PHENANTHROLINE AND 2-METHYLIMIDAZOLE
BHADURI, S
SAPRE, NY
BASU, A
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (03) : 197 - 198
[8] ELECTROCATALYTIC REDUCTION OF CARBON-DIOXIDE BY 2,2'-BIPYRIDINE COMPLEXES OF RHODIUM AND IRIDIUM
BOLINGER, CM
STORY, N
SULLIVAN, BP
MEYER, TJ
[J]. INORGANIC CHEMISTRY, 1988, 27 (25) : 4582 - 4587
[9] [Mn(bipyridyl)(CO)3Br]: An Abundant Metal Carbonyl Complex as Efficient Electrocatalyst for CO2 Reduction
Bourrez, Marc
Molton, Florian
Chardon-Noblat, Sylvie
Deronzier, Alain
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (42) : 9903 - 9906
[10] Electrocatalytic reduction of CO2 into formate with [(eta(5)-Me5C5)M(L)Cl](+) complexes (L = 2,2'-bipyridine ligands; M = Rh(III) and Ir(III))
Caix, C
ChardonNoblat, S
Deronzier, A
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1997, 434 (1-2): : 163 - 170

← 1 2 3 4 5 6 7 →