Design Concepts for N-Heterocyclic Carbene Ligands

被引：53
作者：
Nahra, Fady [1 ,2 ]
Nelson, David J. [3 ]
Nolan, Steven P. [2 ]
机构：
[1] Flemish Inst Technol Res VITO, Boeretang 200, B-2400 Mol, Belgium
[2] Univ Ghent, Dept Chem, Krijgslaan 281-S3, B-9000 Ghent, Belgium
[3] Univ Strathclyde, WestCHEM Dept Pure & Appl Chem, 295 Cathedral St, Glasgow G1 1XL, Lanark, Scotland
来源：
TRENDS IN CHEMISTRY | 2020年 / 2卷 / 12期
关键词：
C-H ACTIVATION; TRANSFER HYDROGENATION; RHODIUM(I) COMPLEXES; IRIDIUM COMPLEXES; METAL-COMPLEXES; GOLD COMPLEXES; NHC COMPLEXES; BEARING; CATALYSTS; BULKY;
D O I：
10.1016/j.trechm.2020.10.003
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
N-heterocyclic carbenes (NHCs) are a widely used class of ligands that have enabled an exciting variety of organometallic chemistry and catalysis. As researchers design and customize these ligands for specific applications, various design concepts have emerged. This review covers several of these design concepts and their impact on and promise for organometallic chemistry and catalysis. These concepts are bulky ligands that remain flexible for substrate binding and reactivity, ring-expanded NHCs with different steric and electronic properties, NHCs appended to supramolecular assemblies that control the microenvironment around the metal center; and NHCs with pendant labile functional groups.
引用
收藏
页码：1096 / 1113
页数：18
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共 113 条
  • [1] Mixed er-NHC/phosphine Pd(ii) complexes and their catalytic activity in the Buchwald-Hartwig reaction under solvent-free conditions
    Ageshina, Alexandra A.
    Sterligov, Grigorii K.
    Rzhevskiy, Sergey A.
    Topchiy, Maxim A.
    Chesnokov, Gleb A.
    Gribanov, Pavel S.
    Melnikova, Elizaveta K.
    Nechaev, Mikhail S.
    Asachenko, Andrey F.
    Bermeshev, Maxim V.
    [J]. DALTON TRANSACTIONS, 2019, 48 (10) : 3447 - 3452
  • [2] Facile Microwave-Assisted Synthesis of Cyclic Amidinium Salts
    Aidouni, Adila
    Bendahou, Soufiane
    Demonceau, Albert
    Delaude, Lionel
    [J]. JOURNAL OF COMBINATORIAL CHEMISTRY, 2008, 10 (06): : 886 - 892
  • [3] Synthesis and characterization of nickel-N-heterocyclic carbenes linked to a calix [6] arene platform and their applications in Suzuki-Miyaura cross-coupling catalysis
    Aloui, Lobna
    Abidi, Rym
    Chetcuti, Michael J.
    [J]. INORGANICA CHIMICA ACTA, 2020, 505 (505)
  • [4] Well-defined coinage metal transfer agents for the synthesis of NHC-based nickel, rhodium and palladium macrocycles
    Andrew, Rhiann E.
    Storey, Caroline M.
    Chaplin, Adrian B.
    [J]. DALTON TRANSACTIONS, 2016, 45 (21) : 8937 - 8944
  • [5] 1,6-Enyne Cyclizations Catalyzed by N-Heterocyclic Carbene Supported Gold Complexes: Deconvoluting Sterics and Electronics
    Arumugam, Kuppuswamy
    Varghese, Bibin
    Brantley, Johnathan N.
    Konda, Sai S. M.
    Lynch, Vincent M.
    Bielawski, Christopher W.
    [J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2014, 2014 (03) : 493 - 497
  • [6] 31PNMR Chemical Shifts of Carbene-Phosphinidene Adducts as an Indicator of the π-Accepting Properties of Carbenes
    Back, Olivier
    Henry-Ellinger, Martin
    Martin, Caleb D.
    Martin, David
    Bertrand, Guy
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (10) : 2939 - 2943
  • [7] Synthetic Routes to N-Heterocyclic Carbene Precursors
    Benhamou, Laure
    Chardon, Edith
    Lavigne, Guy
    Bellemin-Laponnaz, Stephane
    Cesar, Vincent
    [J]. CHEMICAL REVIEWS, 2011, 111 (04) : 2705 - 2733
  • [8] IPr* an easily accessible highly hindered N-heterocyclic carbene
    Berthon-Gelloz, Guillaume
    Siegler, Maxime A.
    Spek, Anthony L.
    Tinant, Bernard
    Reek, Joost N. H.
    Marko, Istvan E.
    [J]. DALTON TRANSACTIONS, 2010, 39 (06) : 1444 - 1446
  • [9] The Suzuki coupling of aryl chlorides in aqueous media catalyzed by in situ generated calix[4]arene-based N-heterocyclic carbene ligands
    Brendgen, Thomas
    Frank, Markus
    Schatz, Juergen
    [J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2006, 2006 (10) : 2378 - 2383
  • [10] Calix[4]arenes with one and two N-linked imidazolium units as precursors of N-heterocyclic carbene complexes. Coordination chemistry and use in Suzuki-Miyaura cross-coupling
    Brenner, Eric
    Matt, Dominique
    Henrion, Mickael
    Teci, Matthieu
    Toupet, Loic
    [J]. DALTON TRANSACTIONS, 2011, 40 (38) : 9889 - 9898
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