N-doped mesoporous carbon nanosheets for supercapacitors with high performance

被引:23
作者
Mo, Yahui [1 ]
Du, Juan [1 ]
Lv, Haijun [1 ]
Zhang, Yue [1 ]
Chen, Aibing [1 ,2 ]
机构
[1] Hebei Univ Sci & Technol, Coll Chem & Pharmaceut Engn, 70 Yuhua Rd, Shijiazhuang 050018, Hebei, Peoples R China
[2] Chinese Acad Sci, Inst Coal Chem, Key Lab Carbon Mat, Beijing, Peoples R China
基金
中国国家自然科学基金;
关键词
Mica; N-doped; Carbon nanosheets; Mesoporous; Supercapacitor; HIERARCHICAL POROUS CARBON; EFFICIENT ELECTRODE MATERIAL; LARGE-SCALE SYNTHESIS; GREEN SYNTHESIS; NITROGEN; COMPOSITES; GRAPHENE; NANOFIBERS; PYROLYSIS; POROSITY;
D O I
10.1016/j.diamond.2020.108206
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Due to the characteristics of thin thickness, rich active sites and short diffusion distance, the carbon nanosheets have been widely used as electrodes for energy storage in supercapacitors. Herein, N-doped mesoporous carbon nanosheets (N-MCS) were prepared by using cheap mica powder as template and resorcinol-formaldehyde (RF) resin as carbon precursor. The ethyl orthosilicate (TEOS) was introduces as porogen to create rich mesopores and to increase surface area. The ethylenediamine can be used not only as catalyst for TEOS hydrolysis and RF resin polymerization, but also as nitrogen dopant. The N-MCS faithfully replicated the template morphology, exhibiting sheet-like morphology, porous and N-doping characteristics, which can effectively improve the electrochemical performance.
引用
收藏
页数:9
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