Azido and Tetrazolo 1,2,4,5-Tetrazine N-Oxides

被引：129

作者：

Chavez, David E. ^{[1
]}

Parrish, Damon A. ^{[2
]}

Mitchell, Lauren ^{[3
]}

Imler, Greg H. ^{[2
]}

机构：

[1] Los Alamos Natl Lab, Explos Sci & Shock Phys, Los Angeles, NM 87545 USA

[2] Naval Res Lab, Struct Matter Lab, 4555 Overlook Ave, Washington, DC 20375 USA

[3] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2017年 / 56卷 / 13期

关键词：

1,2,4,5-tetrazine; azides; energetic materials; N-oxides; tetrazole; PERFORMANCE ENERGETIC MATERIALS; ELEMENTAL FLUORINE; COMPLEXES; EXPLOSIVES; COMPOUND; DENSITY; ANION;

D O I：

10.1002/anie.201612496

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This study presents the synthesis and characterization of the oxidation products of 3,6-diazido-1,2,4,5-tetrazine (1) and 6-amino-[1,5-b]tetrazolo-1,2,4,5-tetrazine (2). 3,6-Diazido-1,2,4,5-tetrazine-1,4-dioxide was produced from oxidation with peroxytrifluoroacetic acid, and more effectively using hypofluorous acid, and 2 can be oxidized to two different products, 6-amino-[1,5-b] tetrazolo-1,2,4,5-tetrazine mono-N-oxide and di-N-oxide. These N-oxide compounds display promising performance properties as energetic materials.

引用

页码：3575 / 3578

页数：4

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