Copper/N, N, N′, N′-Tetramethylethylenediamine-Catalyzed Synthesis of N-Substituted Benzoheterocycles via C-S Cross-Coupling at Ambient Temperature in Water

被引：30

作者：

Zhao, Na ^{[1
]}

Liu, Liang ^{[1
]}

Wang, Fei ^{[1
]}

Li, Jia ^{[1
]}

Zhang, Wu ^{[1
]}

机构：

[1] Anhui Normal Univ, Key Lab Funct Mol Solids, Anhui Lab Mol Based Mat, Coll Chem & Mat Sci,Minist Educ, Wuhu 241000, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2014年 / 356卷 / 11-12期

基金：

中国国家自然科学基金;

关键词：

ambient temperature reaction; copper/N; N; '-tetramethylethylenediamine; (Cu/TMEDA); C-S cross-coupling; N-substituted benzoheterocycles; water; RETINOIC ACID METABOLISM; ONE-POT SYNTHESIS; BOND FORMATION; ROOM-TEMPERATURE; TERMINAL ALKYNES; 3-COMPONENT SYNTHESIS; TANDEM REACTION; 2-AMINOBENZOTHIAZOLES; EFFICIENT; ISOTHIOCYANATES;

D O I：

10.1002/adsc.201400043

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Copper/N, N, N', N'-tetramethylethylenediamine (Cu/TMEDA)-catalyzed ambient temperature tandem reactions of isothiocyanates with 2-iodophenols or 2-iodoanilines in water without the protection of an inert atmosphere are described, which provide a simple, rapid, environmental method for the synthesis of a variety of 2-iminobenzo-1, 3-oxathioles and 2-aminobenzothiazoles in good yields. More important, the present reaction process needs only low amounts of copper catalyst (< 1 mol%) and can yield the products on a gram scale.

引用

页码：2575 / 2579

页数：5

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