H2 and O2 activation by [NiFe]hydrogenases - Insights from model complexes

被引：65
作者：
Ogo, Seiji [1 ,2 ,3 ]
机构：
[1] Kyushu Univ, Ctr Small Mol Energy, Nishi Ku, 744 Moto Oka, Fukuoka 8190395, Japan
[2] Kyushu Univ, Dept Chem & Biochem, Grad Sch Engn, Nishi Ku, 744 Moto Oka, Fukuoka 8190395, Japan
[3] Kyushu Univ, Int Inst Carbon Neutral Energy Res WPI I2CNER, Nishi Ku, 744 Moto Oka, Fukuoka 8190395, Japan
来源：
COORDINATION CHEMISTRY REVIEWS | 2017年 / 334卷
关键词：
FE-ONLY HYDROGENASE; IRON-SULFUR-CLUSTER; CRYSTAL-STRUCTURE; OXYGEN-TOLERANT; ACTIVE-SITE; NIFE; COORDINATION; O-2-TOLERANT; POTENTIALS; OXIDATION;
D O I：
10.1016/j.ccr.2016.07.001
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
H-2 is an important compound from both a biological and a chemical industry perspective. Oxidation and reduction enable H-2 to be used as a source of energy and as a raw material in the manufacture of a variety of useful substances. In nature, hydrogenases (H(2)ases) have been entrusted with the task of activating H-2, making it responsible for part of the Earth's energy circulation system since the birth of the planet. H(2)ases have distinctive active centers and their structures and electronic states can be controlled to produce specific functions. This paper provides an overview of the structures and functions of H(2)ases and their models. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码：43 / 53
页数：11
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