A structural investigation of tris(ethyl acetoacetate)aluminium (III)

被引：5

作者：

Kurajica, S. ^{[1
]}

Popovic, J. ^{[2
]}

Kraljevic, T. Gazivoda ^{[1
]}

Tkalcec, E. ^{[1
]}

Simcic, I. ^{[3
]}

Mandic, V. ^{[1
]}

Altomare, A. ^{[4
]}

Moliterni, A. ^{[4
]}

Rocquefelte, X. ^{[5
]}

机构：

[1] Univ Zagreb, Fac Chem Engn & Technol, Zagreb, Croatia

[2] Rudjer Boskovic Inst, Zagreb, Croatia

[3] Pliva Croatia Ltd, Zagreb, Croatia

[4] CNR, Inst Crystallog, I-70126 Bari, Italy

[5] Univ Nantes, Inst Mat Riaux Jean Rouxel, F-44322 Nantes, France

来源：

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY | 2014年 / 71卷 / 02期

关键词：

Tris(ethyl acetoacetate) aluminium (III); NMR spectroscopy; Structure determination form XRPD; SOL-GEL; ALUMINUM ALKOXIDES; CHELATING-AGENTS; 110; K; STABILITY; COMPLEXES; CHEMISTRY; PHASE;

D O I：

10.1007/s10971-014-3345-1

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Aluminium tris(ethyl acetoacetate), Al(C6H9O3)(3) has been prepared and characterized by means of H-1 and C-13 nuclear magnetic resonance spectroscopy, scanning electron microscopy and X-ray powder diffraction (XRPD). It was determined that two stereoisomeric complexes can be distinguished in the solution: meridional and facial. The crystal structure of Al(C6H9O3)(3) has been determined from XRPD data. The compound crystallizes in the monoclinic space group P2(1)/n.

引用

页码：217 / 223

页数：7

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