Bio-based and Degradable Block Polyester Pressure-Sensitive Adhesives

被引：91
作者：
Chen, Thomas T. D. [1 ]
Carrodeguas, Leticia Pena [1 ]
Sulley, Gregory S. [1 ]
Gregory, Georgina L. [1 ]
Williams, Charlotte K. [1 ]
机构：
[1] Univ Oxford, Dept Chem, Chem Res Lab, 12 Mansfield Rd, Oxford OX1 3TA, England
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2020年 / 59卷 / 52期
基金：
英国工程与自然科学研究理事会;
关键词：
adhesives; block polyesters; degradable polymers; polymers; ring-opening polymerization; RING-OPENING COPOLYMERIZATION; SELECTIVE POLYMERIZATION CATALYSIS; EPOXIDIZED SOYBEAN OIL; ALTERNATING COPOLYMERIZATION; EPSILON-DECALACTONE; CYCLIC ANHYDRIDES; LIMONENE OXIDE; THERMOPLASTIC ELASTOMERS; ALIPHATIC POLYESTERS; PHTHALIC-ANHYDRIDE;
D O I：
10.1002/anie.202006807
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new class of bio-based fully degradable block polyesters are pressure-sensitive adhesives. Bio-derived monomers are efficiently polymerized to make block polyesters with controlled compositions. They show moderate to high peel adhesions (4-13 N cm(-1)) and controllable storage and loss moduli, and they are removed by adhesive failure. Their properties compare favorably with commercial adhesives or bio-based polyester formulations but without the need for tackifier or additives.
引用
收藏
页码：23450 / 23455
页数：6
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