Structure and Thermal Behavior of a Nickel Complex Based on a V-Shaped Bis(4-(1H-imidazol-1-yl)phenyl)amine Ligand

被引:3
作者
Jiao, Yan [1 ]
Wang, Zhe [1 ]
Qiu, Yu [1 ]
He, Jing-Man [1 ]
Chen, Min-dong [1 ]
机构
[1] Nanjing Univ Informat Sci Technol, Sch Environm Sci & Engn, Jiangsu Key Lab Atmospher Environm Monitoring & P, Innovat Res Lab Energy & Environm Catalysis, Nanjing 210044, Jiangsu, Peoples R China
关键词
Coordination Polymer; Crystallography Report; Spray Mass Spectrometry; Coordinate Water Mole; Adjacent Phenyl Ring;
D O I
10.1134/S1063774515070317
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
A new coordination polymer {[Ni(BIPA)(bpdc)(H2O)(2)]} (n) has been prepared based on a new V-shaped bis(4-(1H-imidazol-1-yl)phenyl)amine (BIPA) ligand. Complex was characterized by elemental analysis, IR spectra, X-ray powder diffraction, thermal analysis and single crystal X-ray analysis. Complex exhibits a 1D -> 3D structure. Hydrogen bonds play an important role in the formation of supramolecular network structure. Thermal analysis indicates that complex exhibits a high thermal stability.
引用
收藏
页码:1013 / 1018
页数:6
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