Synthesis of the first unsymmetrical macroheterocycle containing endocyclic phosphorus atoms from pyrocatechol and hydroquinone

被引：1

作者：

Blokhin, Yu. I. ^{[1
]}

Kornilov, K. N. ^{[1
]}

Volchenkova, Yu. V. ^{[1
]}

机构：

[1] Moscow State Univ Technol & Management, Moscow 109004, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2009年 / 79卷 / 02期

关键词：

General Chemistry; Hydroquinone; Macrocycle; Pyrocatechol; Stepwise Mode;

D O I：

10.1134/S1070363209020066

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first unsymmetrical phosphorus(III)-containing macrocycle having hydroquinone and pyrocatechol fragments, N,N,N',N'-tetraethyl-2,4,11,13-tetraoxa-3,12-diphosphatricyclo[12.2.2.0(5,10)]octadeca-1(16),5,7,9,14,17 hexaene-3,12-diamine, was synthesized in a stepwise mode from hexaethylphosphorous triamide, hydroquinone, and pyrocatechol. The product was converted into the corresponding P,P'-dioxide and P,P'-disulfide.

引用

页码：200 / 202

页数：3