Synthesis and Properties of a Novel 3D Europium Coordination Polymer with Helical Chain and (3,6)-Connected rtl Net

被引:2
|
作者
Liu, Zhifeng [1 ]
Lai, Bowen [2 ]
Wen, Huiliang [1 ]
Robbins, Julianne [3 ]
Huang, Nei [4 ]
机构
[1] Nanchang Univ, State Key Lab Food Sci & Technol, Nanchang 330047, Jiangxi, Peoples R China
[2] Nanchang Inst Food & Drug Control, Chem Anal Dept, Nanchang 330038, Jiangxi, Peoples R China
[3] Georgia Inst Technol, Sch Chem & Biochem, Atlanta, GA 30332 USA
[4] Jiangxi Sinograin Qual Supervis Ctr, Nanchang 330000, Jiangxi, Peoples R China
关键词
europium coordination polymer; helix; topological structure; luminescence; magnetism; METAL-ORGANIC FRAMEWORKS; LUMINESCENT PROPERTIES; TRICARBOXYLATE LIGAND; CRYSTAL-STRUCTURES; ACID; SBUS; ARCHITECTURE; COMPLEXES; CLUSTERS; ZN;
D O I
10.1002/cjoc.201600466
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first coordination polymer of 2,2'-((4-carboxymethyl-1,3-phenylene)bis(oxy)) diacetic acid (H3L) with europium(III) ion, [Eu(L)(H2O)]center dot 3H(2)O (1), has been hydrothermally synthesized and structurally characterized. Complex 1 exhibits a 3D coordination polymer with helical chain and rtl topology of the point symbol (4.6(2))(2)(4(2).6(10).8(3)) based on [Eu-2(COO)(4)] as secondary building unit (SBU). Furthermore, the luminescent and magnetic properties of complex 1 are studied.
引用
收藏
页码:1304 / 1308
页数:5
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