Corrosion behaviour of Mg/Al alloys with composite coatings

被引:45
|
作者
Pardo, A. [1 ]
Merino, M. C. [1 ]
Mohedano, M. [1 ]
Casajus, P. [1 ]
Coy, A. E. [2 ]
Arrabal, R. [1 ]
机构
[1] Univ Complutense, Fac Quim, Dept Ciencia Mat, E-28040 Madrid, Spain
[2] Univ Manchester, Sch Mat, Ctr Corros & Protect, Manchester M60 1QD, Lancs, England
来源
SURFACE & COATINGS TECHNOLOGY | 2009年 / 203卷 / 09期
关键词
Magnesium alloys; Al/SiC coatings; Corrosion; Composites; Thermal spraying; THERMAL SPRAY COATINGS; AL-SICP COMPOSITES; WEAR BEHAVIOR; ALUMINUM; MICROSTRUCTURE;
D O I
10.1016/j.surfcoat.2008.10.030
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The corrosion behaviour of aluminium/silicon carbide (Al/SiC) composite coatings deposited by thermal spray on AZ31, AZ80 and AZ91D magnesium-aluminium alloys was investigated by electrochemical and gravimetric measurements in 3.5 wt.% NaCl solution at 22 degrees C. Corrosion products were examined by scanning electron microscopy (SEM), energy dispersive X-ray (EDX) analysis and low-angle X-ray diffraction (XRD). Al/SiC composite coatings in the as-sprayed state revealed high level of porosity with poor bonding at the Al/SiC and coating/substrate interfaces, which facilitated degradation of the magnesium substrates by a mechanism of galvanic corrosion. Cold-pressing post-treatment produced more compact coatings with improved corrosion performance in 3.5 wt.% NaCl compared with as-sprayed coatings. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:1252 / 1263
页数:12
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