Porous and dense Ni hollow fibre membranes

被引:36
作者
Meng, Bo [2 ]
Tana, Xiaoyao [2 ]
Menga, Xiuxia [2 ]
Qiao, Shizhang [1 ]
Liu, Shaomin [1 ]
机构
[1] Univ Queensland, Sch Engn, ARC Ctr Excellence Funct Nanomat, Brisbane, Qld 4072, Australia
[2] Shandong Univ Technol, Sch Chem Engn, Zibo 255049, Peoples R China
基金
中国国家自然科学基金;
关键词
Inorganic Materials; X-ray diffraction; Microstructure; HYDROGEN SEPARATION; COMPOSITE MEMBRANES; NICKEL MEMBRANE; ALLOY MEMBRANE; DEHYDROGENATION; FABRICATION; PERMEATION;
D O I
10.1016/j.jallcom.2008.02.106
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Nickel hollow fibre membranes were prepared by extruding a polymer solution containing suspended nickel (Ni) powder to green hollow fibres, which were then sintered at elevated temperature under an argon atmosphere. The hollow fibres were characterized by a scanning electron microscope (SEM) X-ray, diffractometer (XRD), mercury porosimeter, gas permeation test and conductance measurements. Porous Ni hollow fibres with micron-sized pore structures can be obtained directly by sintering the green fibre at relatively lower temperatures. Heated at a higher temperature (i.e., 950 degrees C), the Ni hollow fibres became gas-tight membranes which are of great interest for hydrogen separation. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:461 / 464
页数:4
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