trans-Dichloridobis[tris(2-methoxyphenyl)phosphine]palladium(II)

被引：1

作者：

van Blerk, Charmaine ^{[1
]}

Holzapfel, Cedric W. ^{[1
]}

机构：

[1] Univ Johannesburg, Dept Chem, ZA-2006 Johannesburg, South Africa

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷

关键词：

CARBON-MONOXIDE; ETHENE;

D O I：

10.1107/S1600536809040719

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The structure of the title compound, [PdCl(2)(C(21)H(21)O(3)P)(2)], shows a nearly square-planar geometry for the Pd(II) atom within the Cl(2)Pd[P(PhOMe)(3)](2) ligand set. The Pd(II) atom sits on a centre of inversion and therefore the asymmetric unit contains one half-molecule, i.e. half of one Pd(II) atom, one Cl atom and one tris(2-methoxyphenyl) phosphine ligand.

引用

页码：M1342 / U916

页数：9

共 3 条

[1] trans-Dichloridobis[tris(4-methoxyphenyl)phosphine]palladium(II) benzene monosolvate
van Blerk, Charmaine
Holzapfel, Cedric W.
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1536 - U379
[2] trans-Bis[bis(2-methoxyphenyl)phenylphosphine-κP]dichloridopalladium(II)
van Blerk, Charmaine
Holzapfel, Cedric W.
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1341 - U907
[3] New carboalkoxybis(triphenylphosphine)palladium(II) cationic complexes: Synthesis, characterization, reactivity and role in the catalytic hydrocarboalkoxylation of ethene. X-ray structure of trans-[Pd(COOMe)(TsO)(PPh3)2]•2CHCl3
Amadio, E.
Cavinato, G.
Dolmella, A.
Ronchin, L.
Toniolo, L.
Vavasori, A.
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2009, 298 (1-2) : 103 - 110

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