Catalytic reaction of methyl formate with amines to formamides

被引：58

作者：

Deutsch, Jens ^{[1
]}

Eckelt, Reinhard ^{[1
]}

Koeckritz, Angela ^{[1
]}

Martin, Andreas ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Catalysis, D-18059 Rostock, Germany

来源：

TETRAHEDRON | 2009年 / 65卷 / 50期

关键词：

Amides; Amines; Formylation; Homogeneous catalysis; SUPERCRITICAL CARBON-DIOXIDE; HOMOGENEOUS CATALYSIS; N-FORMYLATION; FORMIC-ACID; HYDROGENATION; ESTERS; ALKYL; REDUCTION; COMPLEXES; SECONDARY;

D O I：

10.1016/j.tet.2009.10.047

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A feasible procedure of using methyl formate as cheap reagent for the conversion of aliphatic and aromatic amines into formamides with high yields is reported. The improved amine formylation method proceeds mainly at room temperature and in presence of bicyclic guanidines as catalysts. A verifiable key intermediate of outstanding formylating activity is generated from methyl formate and the catalyst in the reaction mixture. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：10365 / 10369

页数：5

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