Hydrosilylation of carbonyls over electron-enriched Ni sites of intermetallic compound Ni3Ga heterogeneous catalyst

被引：4
|
作者：
Takayama, Tomoaki [1 ]
Kariya, Rio [1 ]
Nakaya, Yuki [2 ]
Furukawa, Shinya [2 ,3 ,4 ]
Yamazoe, Seiji [3 ,4 ,5 ]
Komatsu, Takayuki [1 ]
机构：
[1] Tokyo Inst Technol, Dept Chem, Sch Sci, Meguro Ku, 2-12-1-E1-10 Ookayama, Tokyo 1528551, Japan
[2] Hokkaido Univ, Inst Catalysis, Kita Ku, N21,W10, Sapporo, Hokkaido 0010021, Japan
[3] Kyoto Univ, Elements Strategy Initiat Catalysts & Batteries E, Nishikyo Ku, 1-30 Goryo Ohara, Kyoto 6158245, Japan
[4] Japan Sci & Technol Agcy, PRESTO, Chiyoda Ku, Tokyo 1020076, Japan
[5] Tokyo Metropolitan Univ, Grad Sch Sci, Dept Chem, 1-1 Minami Osawa, Hachioji, Tokyo 1920397, Japan
来源：
CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 35期
关键词：
REDUCTION; COMPLEXES; ENONES;
D O I：
10.1039/d0cc07916b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Nanoparticulate intermetallic compound Ni3Ga supported on SiO2 has emerged as a highly efficient catalyst for the hydrosilylation of carbonyls, such as aldehydes and ketones, at room temperature. Formation of electron-enriched Ni via alloying with Ga is the key to the catalytic performance.
引用
收藏
页码：4239 / 4242
页数：4
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