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Microwave-assisted intramolecular reductive Heck in aqueous medium: Synthesis of 3,3′-Disubstituted heterocyclic compounds
被引:5
作者:
Ramesh, Karu
[1
]
Satyanarayana, Gedu
[1
]
机构:
[1] Indian Inst Technol Hyderabad, Dept Chem, Sangareddy 502285, Telangana, India
关键词:
Pd]-catalysis;
Reductive Heck;
Microwave;
Water;
DOMINO PALLADIUM CATALYSIS;
RADICAL CYCLIZATION;
ALPHA-ARYLATION;
METAL;
NANOPARTICLES;
ALKYL;
DERIVATIVES;
INDOLINES;
OXINDOLES;
ALCOHOLS;
D O I:
10.1016/j.jorganchem.2019.120963
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
Heterocyclic products have been accomplished using microwave-assisted [Pd]-catalyzed intramolecular reductive Heck coupling. The protocol found suitable in delivering indolines, oxindoles, and dihydrobenzofurans. Notably, the process was successful in sole aqueous medium and furnished the products bearing a quaternary carbon center. (C) 2019 Elsevier B.V. All rights reserved.
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页数:7
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