Adsorption of copper and nickel on Na-bentonite

被引:127
作者
Liu Zhi-rong [1 ]
Zhou Shao-qi [1 ]
机构
[1] S China Univ Technol, Coll Environm Sci & Technol, Guangzhou 510006, Guangdong, Peoples R China
关键词
Na-bentonite; Copper; Nickel; Adsorption; Isotherm; Kinetics; HEAVY-METALS; SORPTION; REMOVAL; IONS; PH;
D O I
10.1016/j.psep.2009.09.001
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The removal of copper and nickel from aqueous solution on the Na-bentonite has been studied under static conditions. Experiments were carried out as a function of solution pH, dosage of Na-bentonite, contact time and temperature. The adsorption equilibrium for nickel and copper onto Na-bentonite is reached in 200 min. The adsorption of copper and nickel is pH dependent in the pH range 2-9. The kinetic process of adsorption can be described by the pseudo-second-order kinetic equation excellently and the adsorption isotherm be fitted to the Langmuir model by means of regression analyses very well. The adsorption capacities follow the order of Cu2+ > Ni2+ in single-component systems and competitive adsorption capacities in order decreasing is Cu2+ > Ni2+ in binary-component systems. (C) 2009 The Institution of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:62 / 66
页数:5
相关论文
共 14 条
[1]   Adsorption of heavy metals on Na-montmorillonite. Effect of pH and organic substances [J].
Abollino, O ;
Aceto, M ;
Malandrino, M ;
Sarzanini, C ;
Mentasti, E .
WATER RESEARCH, 2003, 37 (07) :1619-1627
[2]   The adsorption of Cu(II) ions on bentonite - a kinetic study [J].
Al-Qunaibit, MH ;
Mekhemer, WK ;
Zaghloul, AA .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2005, 283 (02) :316-321
[3]   Eu(III) adsorption/desorption on Na-bentonite: Experimental and modeling studies [J].
Guo, Zhijun ;
Xu, Jiang ;
Shi, Keliang ;
Tang, Yuqin ;
Wu, Wangsuo ;
Tao, Zuyi .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2009, 339 (1-3) :126-133
[4]   The kinetics of sorption of divalent metal ions onto sphagnum moss peat [J].
Ho, YS ;
McKay, G .
WATER RESEARCH, 2000, 34 (03) :735-742
[5]   THE STABILITY OF TRANSITION-METAL COMPLEXES [J].
IRVING, H ;
WILLIAMS, RJP .
JOURNAL OF THE CHEMICAL SOCIETY, 1953, (OCT) :3192-3210
[6]   Use of immobilized bentonite in removal of heavy metals from wastewater [J].
Kapoor, A ;
Viraraghavan, T .
JOURNAL OF ENVIRONMENTAL ENGINEERING-ASCE, 1998, 124 (10) :1020-1024
[7]   Heavy metal removal from water by sorption using surfactant-modified montmorillonite [J].
Lin, SH ;
Juang, RS .
JOURNAL OF HAZARDOUS MATERIALS, 2002, 92 (03) :315-326
[8]  
Liu Y, 2000, Chin J Dent Res, V3, P15
[9]   EFFECTS OF AQUEOUS AL, CD, CU, FE(II), NI, AND ZN ON PB IMMOBILIZATION BY HYDROXYAPATITE [J].
MA, QY ;
TRAINA, SJ ;
LOGAN, TJ ;
RYAN, JA .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1994, 28 (07) :1219-1228
[10]   Single- and multi-component adsorption of cadmium and zinc using activated carbon derived from bagasse - an agricultural waste [J].
Mohan, D ;
Singh, KP .
WATER RESEARCH, 2002, 36 (09) :2304-2318