Tuning the Lewis acidity of metal-organic frameworks for enhanced catalysis

被引：12

作者：

Devulapalli, Venkata Swaroopa Datta ^{[1
]}

Richard, Melissandre ^{[1
]}

Luo, Tian-Yi ^{[2
]}

De Souza, Mattheus L. ^{[2
]}

Rosi, Nathaniel L. ^{[2
]}

Borguet, Eric ^{[1
]}

机构：

[1] Temple Univ, Dept Chem, Philadelphia, PA 19122 USA

[2] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15261 USA

来源：

DALTON TRANSACTIONS | 2021年 / 50卷 / 09期

关键词：

CHEMICAL WARFARE AGENTS; REACTIVE ADSORPTION; SIMULANT DMMP; HYDROLYSIS; DEGRADATION; CAPTURE; DESIGN; SIZE;

D O I：

10.1039/d1dt00180a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The kinetics of hydrolysis of dimethyl nitrophenyl phosphate (DMNP), a simulant of the nerve agent Soman, was studied and revealed transition metal salts as catalysts. The relative rates of DMNP hydrolysis by zirconium and hafnium chlorides are in accordance with their Lewis acidity. In situ conversion of zirconium chloride to zirconium oxy-hydroxide was identified as the key step. We propose a precursor-MOF activity relationship.

引用

页码：3116 / 3120

页数：5

共 50 条

[31] Metal-Organic Frameworks for Phthalate Capture
Gulcay-Ozcan, Ezgi
Iacomi, Paul
Brantuas, Pedro F.
Rioland, Guillaume
Maurin, Guillaume
Devautour-Vinot, Sabine
ACS APPLIED MATERIALS & INTERFACES, 2023, 15 (41) : 48216 - 48224
[32] An Ising model for metal-organic frameworks
Hoeft, Nicolas
Horbach, Juergen
Martin-Mayor, Victor
Seoane, Beatriz
JOURNAL OF CHEMICAL PHYSICS, 2017, 147 (08)
[33] Metal-organic framework containing Bronsted acidity and Lewis acidity for efficient conversion glucose to levulinic acid
Qu, Haonan
Liu, Bingyi
Gao, Guohua
Ma, Yiming
Zhou, Yanmei
Zhou, Hua
Li, Li
Li, Yonghong
Liu, Shengjian
FUEL PROCESSING TECHNOLOGY, 2019, 193 : 1 - 6
[34] Tuning the Adsorption Properties of Metal-Organic Frameworks through Coadsorbed Ammonia
Chapman, Eric
Ullah, Saif
Wang, Hao
Feng, Liang
Wang, Kunyu
Zhou, Hong-Cai
Li, Jing
Thonhauser, Timo
Tan, Kui
ACS APPLIED MATERIALS & INTERFACES, 2021, 13 (36) : 43661 - 43667
[35] Bimetallic Metal-Organic Frameworks: Probing the Lewis Acid Site for CO2 Conversion
Zou, Ruyi
Li, Pei-Zhou
Zeng, Yong-Fei
Liu, Jia
Zhao, Ruo
Duan, Hui
Luo, Zhong
Wang, Jin-Gui
Zou, Ruqiang
Zhao, Yanli
SMALL, 2016, 12 (17) : 2334 - 2343
[36] New Opportunities in Metal-Organic Framework Catalysis: From Bifunctional to Frustrated Lewis Pairs Catalysis
Dhakshinamoorthy, Amarajothi
Asiri, Abdullah M.
Garcia, Hermenegildo
CHEMISTRY-A EUROPEAN JOURNAL, 2022, 29 (38)
[37] Teaching Metal-Organic Frameworks to Conduct: Ion and Electron Transport in Metal-Organic Frameworks
Kharod, Ruby A.
Andrews, Justin L.
Dinc, Mircea
ANNUAL REVIEW OF MATERIALS RESEARCH, 2022, 52 : 103 - 128
[38] Innovative strategies in metal-organic frameworks for enhanced electrochemiluminescence biosensors
Song, Kai
Zhao, Wei
Zhou, Yan
Liu, Duo
Chu, Paul K.
COORDINATION CHEMISTRY REVIEWS, 2024, 520
[39] Nanozyme Decorated Metal-Organic Frameworks for Enhanced Photodynamic Therapy
Zhang, Yan
Wang, Faming
Liu, Chaoqun
Wang, Zhenzhen
Kang, LiHua
Huang, Yanyan
Dong, Kai
Ren, Jinsong
Qu, Xiaogang
ACS NANO, 2018, 12 (01) : 651 - 661
[40] Docking in Metal-Organic Frameworks
Li, Qiaowei
Zhang, Wenyu
Miljanic, Ognjen S.
Sue, Chi-Hau
Zhao, Yan-Li
Liu, Lihua
Knobler, Carolyn B.
Stoddart, J. Fraser
Yaghi, Omar M.
SCIENCE, 2009, 325 (5942) : 855 - 859

← 1 2 3 4 5 →