Relationships between Lead Halide Perovskite Thin-Film Fabrication, Morphology, and Performance in Solar Cells

被引：231

作者：

Sharenko, Alexander ^{[1
]}

Toney, Michael F. ^{[1
]}

机构：

[1] SLAG Natl Accelerator Lab, Stanford Synchrotron Radiat Lightsource, Menlo Pk, CA 94025 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2016年 / 138卷 / 02期

关键词：

SOLUTION-PROCESSED PEROVSKITE; PLANAR CH3NH3PBI3 PEROVSKITE; SINGLE-CRYSTALLINE GRAINS; CONTROLLED HUMIDITY; HYBRID PEROVSKITE; EFFICIENCY; HYSTERESIS; TRIHALIDE; PASSIVATION; CHLORIDE;

D O I：

10.1021/jacs.5b10723

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solution-processed lead halide perovskite thin-film solar cells have achieved power conversion efficiencies comparable to those obtained with several commercial photovoltaic technologies in a remarkably short period of time. This rapid rise in device efficiency is largely the result of the development of fabrication protocols capable of producing continuous, smooth perovskite films with micrometer-sized grains. Further developments in film fabrication and morphological control are necessary, however, in order for perovskite solar cells to reliably and reproducibly approach their thermodynamic efficiency limit. This Perspective discusses the fabrication of lead halide perovskite thin films, while highlighting the processing-property-performance relationships that have emerged from the literature, and from this knowledge, suggests future research directions.

引用

页码：463 / 470

页数：8

共 81 条

[1] Supramolecular Halogen Bond Passivation of Organic-Inorganic Halide Perovskite Solar Cells [J].

Abate, Antonio ;

Saliba, Michael ;

Hollman, Derek J. ;

Stranks, Samuel D. ;

Wojciechowski, Konrad ;

Avolio, Roberto ;

Grancini, Giulia ;

Petrozza, Annamaria ;

Snaith, Henry J. .

NANO LETTERS, 2014, 14 (06) :3247-3254

[2] Highly Reproducible Perovskite Solar Cells with Average Efficiency of 18.3% and Best Efficiency of 19.7% Fabricated via Lewis Base Adduct of Lead(II) Iodide [J].

Ahn, Namyoung ;

Son, Dae-Yong ;

Jang, In-Hyuk ;

Kang, Seong Min ;

Choi, Mansoo ;

Park, Nam-Gyu .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (27) :8696-8699

[3] Hybrid Organic-Inorganic Perovskites (HOIPs): Opportunities and Challenges [J].

Berry, Joseph ;

Buonassisi, Tonio ;

Egger, David A. ;

Hodes, Gary ;

Kronik, Leeor ;

Loo, Yueh-Lin ;

Lubomirsky, Igor ;

Marder, Seth R. ;

Mastai, Yitzhak ;

Miller, Joel S. ;

Mitzi, David B. ;

Paz, Yaron ;

Rappe, Andrew M. ;

Riess, Ilan ;

Rybtchinski, Boris ;

Stafsudd, Oscar ;

Stevanovic, Vladan ;

Toney, Michael F. ;

Zitoun, David ;

Kahn, Antoine ;

Ginley, David ;

Cahen, David .

ADVANCED MATERIALS, 2015, 27 (35) :5102-5112

[4] Non-wetting surface-driven high-aspect-ratio crystalline grain growth for efficient hybrid perovskite solar cells [J].

Bi, Cheng ;

Wang, Qi ;

Shao, Yuchuan ;

Yuan, Yongbo ;

Xiao, Zhengguo ;

Huang, Jinsong .

NATURE COMMUNICATIONS, 2015, 6

[5] Understanding the formation and evolution of interdiffusion grown organolead halide perovskite thin films by thermal annealing [J].

Bi, Cheng ;

Shao, Yuchuan ;

Yuan, Yongbo ;

Xiao, Zhengguo ;

Wang, Chenggong ;

Gao, Yongli ;

Huang, Jinsong .

JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (43) :18508-18514

[6] Heterogeneous Charge Carrier Dynamics in Organic Inorganic Hybrid Materials: Nanoscale Lateral and Depth-Dependent Variation of Recombination Rates in Methylammonium Lead Halide Perovskite Thin Films [J].

Bischak, Connor G. ;

Sanehira, Erin M. ;

Precht, Jake T. ;

Luther, Joseph M. ;

Ginsberg, Naomi S. .

NANO LETTERS, 2015, 15 (07) :4799-4807

[7] Materials Processing Routes to Trap-Free Halide Perovskites [J].

Buin, Andrei ;

Pietsch, Patrick ;

Xu, Jixian ;

Voznyy, Oleksandr ;

Ip, Alexander H. ;

Comin, Riccardo ;

Sargent, Edward H. .

NANO LETTERS, 2014, 14 (11) :6281-6286

[8] Sequential deposition as a route to high-performance perovskite-sensitized solar cells [J].

Burschka, Julian ;

Pellet, Norman ;

Moon, Soo-Jin ;

Humphry-Baker, Robin ;

Gao, Peng ;

Nazeeruddin, Mohammad K. ;

Graetzel, Michael .

NATURE, 2013, 499 (7458) :316-+

[9] Transformation of the Excited State and Photovoltaic Efficiency of CH3NH3PbI3 Perovskite upon Controlled Exposure to Humidified Air [J].

Christians, Jeffrey A. ;

Miranda Herrera, Pierre A. ;

Kamat, Prashant V. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (04) :1530-1538

[10] The roles of alkyl halide additives in enhancing perovskite solar cell performance [J].

Chueh, Chu-Chen ;

Liao, Chien-Yi ;

Zuo, Fan ;

Williams, Spencer T. ;

Liang, Po-Wei ;

Jen, Alex K-Y .

JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (17) :9058-9062

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