Relationships between Lead Halide Perovskite Thin-Film Fabrication, Morphology, and Performance in Solar Cells

被引：229

作者：

Sharenko, Alexander ^{[1
]}

Toney, Michael F. ^{[1
]}

机构：

[1] SLAG Natl Accelerator Lab, Stanford Synchrotron Radiat Lightsource, Menlo Pk, CA 94025 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2016年 / 138卷 / 02期

关键词：

SOLUTION-PROCESSED PEROVSKITE; PLANAR CH3NH3PBI3 PEROVSKITE; SINGLE-CRYSTALLINE GRAINS; CONTROLLED HUMIDITY; HYBRID PEROVSKITE; EFFICIENCY; HYSTERESIS; TRIHALIDE; PASSIVATION; CHLORIDE;

D O I：

10.1021/jacs.5b10723

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solution-processed lead halide perovskite thin-film solar cells have achieved power conversion efficiencies comparable to those obtained with several commercial photovoltaic technologies in a remarkably short period of time. This rapid rise in device efficiency is largely the result of the development of fabrication protocols capable of producing continuous, smooth perovskite films with micrometer-sized grains. Further developments in film fabrication and morphological control are necessary, however, in order for perovskite solar cells to reliably and reproducibly approach their thermodynamic efficiency limit. This Perspective discusses the fabrication of lead halide perovskite thin films, while highlighting the processing-property-performance relationships that have emerged from the literature, and from this knowledge, suggests future research directions.

引用

页码：463 / 470

页数：8

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