Surface alloying and anomalous diffusion of Bi on Cu(111)

被引:12
作者
van Gastel, R. [1 ]
Kaminski, D. [2 ,3 ]
Vlieg, E. [2 ]
Poelsema, B. [1 ]
机构
[1] Univ Twente, MESA Inst Nanotechnol, NL-7500 AE Enschede, Netherlands
[2] Radboud Univ Nijmegen, IMM, NL-6525 AJ Nijmegen, Netherlands
[3] Univ Life Sci Lublin, Fac Food Sci & Biotechnol, PL-20704 Lublin, Poland
关键词
Low-Energy Electron Microscopy (LEEM); Bismuth; Copper; Surface structure; Morphology; Roughness and topography; Epitaxy; ELECTRON-MICROSCOPY; ATOMIC MECHANISMS; CRYSTAL-SURFACES; NUCLEATION; DEPOSITION; SUBSTRATE; CU(100); BISMUTH; GROWTH; LEED;
D O I
10.1016/j.susc.2009.09.018
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We have used Low-Energy Electron Microscopy (LEEM) to study the formation and structure of the surface alloy of Bi on the Cu(111) surface. As a function of Bi coverage we find a progression from a dilute surface alloy to a root 3 x root 3-R30 degrees structure, which coexists with a Bi overlayer when the Bi coverage exceeds 1/3 ML. At a temperature of 401 K, an unusual formation of alloy domains is observed. The origin of this effect is traced down to the mobility of Bi adatoms, which is found to strongly depend on the Bi coverage of the surface alloy on which they reside. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:3292 / 3296
页数:5
相关论文
共 33 条
  • [11] Atomic mechanisms for the diffusion of Mn atoms incorporated in the Cu(100) surface: An STM study
    Flores, T
    Junghans, S
    Wuttig, M
    [J]. SURFACE SCIENCE, 1997, 371 (01) : 1 - 13
  • [12] Diffusion kinetics in the Pd/Cu(001) surface alloy
    Grant, ML
    Swartzentruber, BS
    Bartelt, NC
    Hannon, JB
    [J]. PHYSICAL REVIEW LETTERS, 2001, 86 (20) : 4588 - 4591
  • [13] DOMAIN-ARRAY MELTING IN THE DIPOLAR LATTICE GAS
    HURLEY, MM
    SINGER, SJ
    [J]. PHYSICAL REVIEW B, 1992, 46 (09) : 5783 - 5787
  • [14] Surface alloys, overlayer and incommensurate structures of Bi on Cu(111)
    Kaminski, D
    Poodt, P
    Aret, E
    Radenovic, N
    Vlieg, E
    [J]. SURFACE SCIENCE, 2005, 575 (03) : 233 - 246
  • [15] Observation of a liquid phase with an orthorhombic orientational order
    Kaminski, D
    Poodt, P
    Aret, E
    Radenovic, N
    Vlieg, E
    [J]. PHYSICAL REVIEW LETTERS, 2006, 96 (05)
  • [16] SURFACE SELF-DIFFUSION ON PT(001) BY AN ATOMIC EXCHANGE MECHANISM
    KELLOGG, GL
    FEIBELMAN, PJ
    [J]. PHYSICAL REVIEW LETTERS, 1990, 64 (26) : 3143 - 3146
  • [17] CORRECTION
    KELLOGG, GL
    [J]. PHYSICAL REVIEW LETTERS, 1990, 65 (07) : 939 - 939
  • [18] FIELD-ION MICROSCOPE STUDIES OF SINGLE-ATOM SURFACE-DIFFUSION AND CLUSTER NUCLEATION ON METAL-SURFACES
    KELLOGG, GL
    [J]. SURFACE SCIENCE REPORTS, 1994, 21 (1-2) : 1 - 88
  • [19] MARCHENKO VI, 1981, JETP LETT+, V33, P381
  • [20] STABILITY OF PERIODIC DOMAIN-STRUCTURES IN A 2-DIMENSIONAL DIPOLAR MODEL
    NG, KO
    VANDERBILT, D
    [J]. PHYSICAL REVIEW B, 1995, 52 (03): : 2177 - 2183