Excess molar enthalpies of binary mixtures containing propylene carbonate plus some n-alkoxy- and n-alkoxyethoxy-ethanols at 288.15, 298.15, and 313.15 K

被引:21
作者
Comelli, F
Francesconi, R
Castellari, C
机构
[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy
[2] CNR, Ctr Studio Fis Macromol, I-40126 Bologna, Italy
关键词
calorimeter; enthalpies; correlation;
D O I
10.1016/S0040-6031(00)00457-3
中图分类号
O414.1 [热力学];
学科分类号
摘要
Excess molar enthalpies, H-m(E), of binary mixtures containing propylene carbonate + six n-alkoxyethanols have been determined using an LKB Row microcalorimeter at 288.15, 298.15, and 313.15 K and at atmospheric pressure. The alkoxyethanols were 2-methoxyethanol, 2-ethoxyethanol, 2-butoxyethanol, 2-(2-methoxyethoxy)ethanol, 2-(2-ethoxyethoxy)ethanol, and 2-(2-butoxyethoxy)ethanol. From the experimental data, deviations in H-m(E) have been determined and fitted to the Redlich-Kister polynomial to estimate the binary interactions parameters. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:89 / 97
页数:9
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