Synthesis and optical property of NaTaO3 nanofibers prepared by electrospinning

被引:19
作者
Yi, Xi [1 ]
Li, Jianlin [1 ]
机构
[1] Shanghai Univ, Coll Mat Sci & Engn, Shanghai 201800, Peoples R China
关键词
NaTaO3; Nanofibers; Electrospinning; Optical property; OXIDE NANOWIRE ARRAYS; PHOTOCATALYTIC DEGRADATION; METHYLENE-BLUE; WATER; O-2; H-2; FABRICATION; MORPHOLOGY; TITANIA; FILMS;
D O I
10.1007/s10971-009-2110-3
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
This paper describes a procedure of preparing sodium tantalite nanofibers for the first time. Sodium tantalite nanofibers were synthesised by electrospinning a sol-gel precursor solution of poly(vinyl pyrrolidone)/sodium tantalite, followed by careful sintering of the as-electrospun composite fibers at 550 A degrees C for 3 h. The morphology, microstructure and crystal phase were investigated by transmission electron microcopy and X-ray diffraction. The optical property was characterized by ultraviolet-visible (UV-vis) spectrometer. Typical nanofibers were with diameter between 70 and 90 nm and length exceeding 0.1 mm. An unusual phenomenon, the red-shift of optical absorption band edge happened, indicated the fabricated NaTaO3 nanofibers were potential good candidates for photocatalytic application. The experiment photodegradation of methylene blue by NaTaO3 nanofibers under UV light irradiation was performed.
引用
收藏
页码:480 / 484
页数:5
相关论文
共 24 条
[1]   Photocatalytic activity of titania fibers obtained by electrospinning [J].
Alves, A. K. ;
Berutti, F. A. ;
Clemens, F. J. ;
Graule, T. ;
Bergmann, C. P. .
MATERIALS RESEARCH BULLETIN, 2009, 44 (02) :312-317
[2]   Structure and electronic properties of solid acids based on tungsten oxide nanostructures [J].
Barton, DG ;
Shtein, M ;
Wilson, RD ;
Soled, SL ;
Iglesia, E .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (04) :630-640
[3]   Investigation of the nanocluster self-assembly process by scanning tunneling microscopy and optical spectroscopy [J].
Chemseddine, A ;
Jungblut, H ;
Boulmaaz, S .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (30) :12546-12551
[4]   Polymer nanofibers assembled by electrospinning [J].
Frenot, A ;
Chronakis, IS .
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2003, 8 (01) :64-75
[5]   Synthesis of nanosized NaTaO3 in low temperature and its photocatalytic performance [J].
He, Y ;
Zhu, YF ;
Wu, NZ .
JOURNAL OF SOLID STATE CHEMISTRY, 2004, 177 (11) :3868-3872
[6]   Influence of structural features on the photocatalytic activity of NaTaO3 powders from different synthesis methods [J].
Hu, Che-Chia ;
Teng, Hsisheng .
APPLIED CATALYSIS A-GENERAL, 2007, 331 (44-50) :44-50
[7]  
KANG H, 2008, INT J PHOTOENERGY, P8
[8]   Highly efficient water splitting into H2 and O2 over lanthanum-doped NaTaO3 photocatalysts with high crystallinity and surface nanostructure [J].
Kato, H ;
Asakura, K ;
Kudo, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (10) :3082-3089
[9]   Water splitting into H2 and O2 on alkali tantalate photocatalysts ATaO3 (A = Li, Na, and K) [J].
Kato, H ;
Kudo, A .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (19) :4285-4292
[10]   Highly efficient decomposition of pure water into H2 and O2 over NaTaO3 photocatalysts [J].
Kato, H ;
Kudo, A .
CATALYSIS LETTERS, 1999, 58 (2-3) :153-155