Enhanced electrochemical performance of vanadium dioxide (B) nanoflowers with graphene nanoribbons support

被引:10
作者
Fan, Zihan [1 ]
Jia, Lina [1 ]
Lin, Cunli [1 ]
Huang, Xiangyue [1 ]
Hu, Xiaolin [1 ]
Zhuang, Naifeng [1 ]
Chen, Jianzhong [1 ]
机构
[1] Fuzhou Univ, Coll Chem, Fuzhou 350116, Peoples R China
来源
RSC ADVANCES | 2016年 / 6卷 / 16期
基金
中国国家自然科学基金;
关键词
LITHIUM-ION BATTERIES; NANOSTRUCTURES HYDROTHERMAL SYNTHESIS; CATHODE MATERIAL; HIGH-CAPACITY; OXIDE; VO2(B); ELECTRODES; COMPOSITE; GROWTH; LI;
D O I
10.1039/c5ra20018k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Specific VO2 (B) nanoflowers and their composite hybridized with graphene nanoribbons (GNRs) are prepared using a moderate H2C2O4 reductant to reduce V2O5 with the molar ratio of H2C2O4 : V2O5 as 3 : 1. The discharge specific capacities and the cycling stabilities of the VO2 (B) cathode material for lithium-ion batteries can be improved by graphenes support. In particular, GNRs support can improve the dispersibility and the electrical conductivity of the VO2 (B) nanoflowers. Thus, VO2 (B)/GNRs (32.2 wt%) composite exhibits excellent electrochemical performance with the high specific capacity of 471.5 mA h g(-1) and the preferable cycling stability.
引用
收藏
页码:13297 / 13302
页数:6
相关论文
共 43 条
  • [1] The synthesis and lithium intercalation electrochemistry of VO2(B) ultra-thin nanowires
    Armstrong, Graham
    Canales, Jesus
    Armstrong, A. Robert
    Bruce, Peter G.
    [J]. JOURNAL OF POWER SOURCES, 2008, 178 (02) : 723 - 728
  • [2] Graphene Quantum Dots Coated VO2 Arrays for Highly Durable Electrodes for Li and Na Ion Batteries
    Chao, Dongliang
    Zhu, Changrong
    Xia, Xinhui
    Liu, Jilei
    Zhang, Xiao
    Wang, Jin
    Liang, Pei
    Lin, Jianyi
    Zhang, Hua
    Shen, Ze Xiang
    Fan, Hong Jin
    [J]. NANO LETTERS, 2015, 15 (01) : 565 - 573
  • [3] Layered vanadium and molybdenum oxides: batteries and electrochromics
    Chernova, Natasha A.
    Roppolo, Megan
    Dillon, Anne C.
    Whittingham, M. Stanley
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (17) : 2526 - 2552
  • [4] High capacity and excellent cyclability of vanadium (IV) oxide in lithium battery applications
    Ding, Ning
    Feng, Xuyong
    Liu, Shuhua
    Xu, Jing
    Fang, Xin
    Lieberwirth, Ingo
    Chen, Chunhua
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2009, 11 (03) : 538 - 541
  • [5] Novel properties of graphene nanoribbons: a review
    Dutta, Sudipta
    Pati, Swapan K.
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (38) : 8207 - 8223
  • [6] Symmetrical MnO2-Carbon Nanotube-Textile Nanostructures for Wearable Pseudocapacitors with High Mass Loading
    Hu, Liangbing
    Chen, Wei
    Xie, Xing
    Liu, Nian
    Yang, Yuan
    Wu, Hui
    Yao, Yan
    Pasta, Mauro
    Alshareef, Husam N.
    Cui, Yi
    [J]. ACS NANO, 2011, 5 (11) : 8904 - 8913
  • [7] Flexible Free-Standing VO2(B) Nanobelt Films as Additive-Free Cathode for Lithium-Ion Batteries
    Huang, Jijiang
    Wang, Xiaofei
    Liu, Junfeng
    Sun, Xiaoming
    Wang, Li
    He, Xiangming
    [J]. INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2011, 6 (05): : 1709 - 1719
  • [8] High electrochemical properties of graphene nanoribbons-hybridized manganese dioxide as cathode material for lithium battery
    Huang, Xiangyue
    Fan, Zihan
    Lin, Cunli
    Jia, Lina
    Lin, Baiwei
    Wang, Jiaqi
    Hu, Xiaolin
    Zhuang, Naifeng
    [J]. JOURNAL OF NANOPARTICLE RESEARCH, 2015, 17 (02)
  • [9] A green and high energy density asymmetric supercapacitor based on ultrathin MnO2 nanostructures and functional mesoporous carbon nanotube electrodes
    Jiang, Hao
    Li, Chunzhong
    Sun, Ting
    Ma, Jan
    [J]. NANOSCALE, 2012, 4 (03) : 807 - 812
  • [10] Hydrothermal synthesis and electrochemical characterization of VO2 (B) with controlled crystal structures
    Jiang, Wentao
    Ni, Juan
    Yu, Ke
    Zhu, Ziqiang
    [J]. APPLIED SURFACE SCIENCE, 2011, 257 (08) : 3253 - 3258