Oxidative addition of C-CN bond to nickel(0) complex: Synthesis and crystal structures of Ni(CN)(o-C6H4CN)(bpy) and Ni(CN) (p-C6H4CN)(bpy)

被引：64

作者：

Abla, M ^{[1
]}

Yamamoto, T ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,RESOURCES UTILIZAT RES LAB,MIDORI KU,YOKOHAMA,KANAGAWA 226,JAPAN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 532卷 / 1-2期

关键词：

nickel; oxidative addition; nitrile; crystal structure;

D O I：

10.1016/S0022-328X(96)06774-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of phthalonitrile and terephthalonitrile with Ni(cod)(bpy) in a THF solution at room temperature lead to oxidative addition of the C-CN bond to give square-planar Ni(CN)(o-C6H4CN)(bpy) (3) and Ni(CN)(p-C6H4CN)(bpy) (4) respectively. Data from elemental analysis, as well as their IR and NMR spectra, agree with the structures. Crystal structures of the complexes 3 and 4 have been determined by X-ray crystallography.

引用

页码：267 / 270

页数：4

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