Spectroscopic characterization of a new type of conducting polymer-clay nanocomposite

被引:92
作者
do Nascimento, GM [1 ]
Constantino, VRL [1 ]
Temperini, MLA [1 ]
机构
[1] Univ Sao Paulo, Inst Quim, Dept Quim Fundamental, BR-05513970 Sao Paulo, Brazil
关键词
D O I
10.1021/ma025571l
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The resonance Raman (RR) characterization of clay nanocomposite formed by the aniline polymerization in the presence of smectite clay Swy2 montmorillonite (MMT) was presented. The X-ray diffraction was used to follow the anilinium intercalation and polymerization during the in situ polymerization. The results showed that the prepared polymer exhibited tail-to-tail and head-to-tail segments.
引用
收藏
页码:7535 / 7537
页数:3
相关论文
共 22 条
  • [1] Polymer-layered silicate nanocomposites: Preparation, properties and uses of a new class of materials
    Alexandre, Michael
    Dubois, Philippe
    [J]. Materials Science and Engineering: R: Reports, 2000, 28 (1-2) : 1 - 63
  • [2] Biswas M, 2000, J APPL POLYM SCI, V77, P2948, DOI 10.1002/1097-4628(20000923)77:13<2948::AID-APP18>3.0.CO
  • [3] 2-F
  • [4] INTERCALATION OF POLYANILINE IN MONTMORILLONITE AND ZEOLITE
    CHANG, TC
    HO, SY
    CHAO, KJ
    [J]. JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 1992, 39 (03) : 209 - 212
  • [5] Comparison of secondary doping and thermal treatment in poly(diphenylamine) and polyaniline monitored by resonance Raman spectroscopy
    do Nascimento, GM
    da Silva, JEP
    de Torresi, SIC
    Temperini, MLA
    [J]. MACROMOLECULES, 2002, 35 (01) : 121 - 125
  • [6] Electropolymerization of polyaniline/montmorillonite nanocomposite
    Feng, B
    Su, YZ
    Song, JH
    Kong, KC
    [J]. JOURNAL OF MATERIALS SCIENCE LETTERS, 2001, 20 (04) : 293 - 294
  • [7] Synthesis and characterization of a conductive polyaniline/clay hybrid system
    Frisch, HL
    Xi, BW
    Qin, YC
    Rafailovich, M
    Yang, NL
    Yan, XZ
    [J]. HIGH PERFORMANCE POLYMERS, 2000, 12 (04) : 543 - 549
  • [8] ELECTROPOLYMERIZATION OF ANILINE INTERCALATED IN MONTMORILLONITE
    INOUE, H
    YONEYAMA, H
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1987, 233 (1-2): : 291 - 294
  • [9] Physical characterization of polyaniline-Na+-montmorillonite nanocomposite intercalated by emulsion polymerization
    Kim, BH
    Jung, JH
    Kim, JW
    Choi, HJ
    Joo, J
    [J]. SYNTHETIC METALS, 2001, 117 (1-3) : 115 - 118
  • [10] Effect of dopant and clay on nanocomposites of polyaniline (PAN) intercalated into Na+-montmorillonite (N+-MMT)
    Kim, BH
    Jung, JH
    Kim, JW
    Choi, HJ
    Joo, J
    [J]. SYNTHETIC METALS, 2001, 121 (1-3) : 1311 - 1312