Rapid and sensitive detection of nitroaromatic explosives by using new 3D lanthanide phosphonates

被引：73
作者：
Fu, Ruibiao [1 ]
Hu, Shengmin [1 ]
Wu, Xintao [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
来源：
JOURNAL OF MATERIALS CHEMISTRY A | 2017年 / 5卷 / 05期
基金：
美国国家科学基金会;
关键词：
METAL-ORGANIC FRAMEWORK; HIGHLY SELECTIVE DETECTION; PROTON CONDUCTION; LUMINESCENCE PROPERTIES; HIGH-NUCLEARITY; MAGNESIUM MOF; SOLID-STATE; SENSOR; NITROBENZENE; SYMMETRY;
D O I：
10.1039/c6ta10152f
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A luminescent terbiumphosphonate metal-organic framework (MOF) exhibits a remarkable capability to rapidly detect traces of nitro-aromatic explosives (as low as 66 ppb) through luminescence quenching. Its sensitivity, fast response, facile synthesis, low usage (less than 0.1 mg), cheapness, and good stability make it one of the most powerful nitroaromatic explosive sensors known.
引用
收藏
页码：1952 / 1956
页数：5
相关论文
共 42 条
  • [11] Luminescent metal-organic frameworks for chemical sensing and explosive detection
    Hu, Zhichao
    Deibert, Benjamin J.
    Li, Jing
    [J]. CHEMICAL SOCIETY REVIEWS, 2014, 43 (16) : 5815 - 5840
  • [12] Lanthanide(III) oxalatophosphonates: syntheses, crystal structures and luminescence properties
    Jiao, Cheng-Qi
    Zhang, Ji-Cai
    Zhao, Yan
    Sun, Zhen-Gang
    Zhu, Yan-Yu
    Dai, Lu-Lu
    Shi, Shao-Ping
    Zhou, Wei
    [J]. DALTON TRANSACTIONS, 2014, 43 (04) : 1542 - 1549
  • [13] Selective and Sensitive Aqueous-Phase Detection of 2,4,6-Trinitrophenol (TNP) by an Amine-Functionalized Metal-Organic Framework
    Joarder, Biplab
    Desai, Aamod V.
    Samanta, Partha
    Mukherjee, Soumya
    Ghosh, Sujit K.
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (03) : 965 - 969
  • [14] A dual functional MOF as a luminescent sensor for quantitatively detecting the concentration of nitrobenzene and temperature
    Ma, Dingxuan
    Li, Baiyan
    Zhou, Xiaojing
    Zhou, Qi
    Liu, Kang
    Zeng, Guang
    Li, Guanghua
    Shi, Zhan
    Feng, Shouhua
    [J]. CHEMICAL COMMUNICATIONS, 2013, 49 (79) : 8964 - 8966
  • [15] A fluorescent metal-organic framework for highly selective detection of nitro explosives in the aqueous phase
    Nagarkar, Sanjog S.
    Desai, Aamod V.
    Ghosh, Sujit K.
    [J]. CHEMICAL COMMUNICATIONS, 2014, 50 (64) : 8915 - 8918
  • [16] Highly Selective Detection of Nitro Explosives by a Luminescent Metal-Organic Framework
    Nagarkar, Sanjog S.
    Joarder, Biplab
    Chaudhari, Abhijeet K.
    Mukherjee, Soumya
    Ghosh, Sujit K.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (10) : 2881 - 2885
  • [17] Remarkable Pressure Responses of Metal-Organic Frameworks: Proton Transfer and Linker Coiling in Zinc Alkyl Gates
    Ortiz, Aurelie U.
    Boutin, Anne
    Gagnon, Kevin J.
    Clearfield, Abraham
    Coudert, Francois-Xavier
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (32) : 11540 - 11545
  • [18] A colorimetric and fluorescent chemosensor for the detection of an explosive-2,4,6-trinitrophenol (TNP)
    Peng, Yu
    Zhang, Ai-Jiang
    Dong, Ming
    Wang, Ya-Wen
    [J]. CHEMICAL COMMUNICATIONS, 2011, 47 (15) : 4505 - 4507
  • [19] Proton Conduction in a Phosphonate-Based Metal-Organic Framework Mediated by Intrinsic "Free Diffusion inside a Sphere"
    Pili, Simona
    Argent, Stephen P.
    Morris, Christopher G.
    Rought, Peter
    Garcia-Sakai, Victoria
    Silverwood, Ian P.
    Easun, Timothy L.
    Li, Ming
    Warren, Mark R.
    Murray, Claire A.
    Tang, Chiu C.
    Yang, Sihai
    Schroeder, Martin
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (20) : 6352 - 6355
  • [20] Copper Lanthanide Phosphonate Cages: Highly Symmetric {Cu3Ln9P6} and {Cu6Ln6P6} Clusters with C3v and D3h Symmetry
    Pineda, Eufemio Moreno
    Heesing, Christian
    Tuna, Floriana
    Zheng, Yan-Zhen
    McInnes, Eric J. L.
    Schnack, Juergen
    Winpenny, Richard E. P.
    [J]. INORGANIC CHEMISTRY, 2015, 54 (13) : 6331 - 6337
12345