Rapid and sensitive detection of nitroaromatic explosives by using new 3D lanthanide phosphonates

被引:73
作者
Fu, Ruibiao [1 ]
Hu, Shengmin [1 ]
Wu, Xintao [1 ]
机构
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
基金
美国国家科学基金会;
关键词
METAL-ORGANIC FRAMEWORK; HIGHLY SELECTIVE DETECTION; PROTON CONDUCTION; LUMINESCENCE PROPERTIES; HIGH-NUCLEARITY; MAGNESIUM MOF; SOLID-STATE; SENSOR; NITROBENZENE; SYMMETRY;
D O I
10.1039/c6ta10152f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A luminescent terbiumphosphonate metal-organic framework (MOF) exhibits a remarkable capability to rapidly detect traces of nitro-aromatic explosives (as low as 66 ppb) through luminescence quenching. Its sensitivity, fast response, facile synthesis, low usage (less than 0.1 mg), cheapness, and good stability make it one of the most powerful nitroaromatic explosive sensors known.
引用
收藏
页码:1952 / 1956
页数:5
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