Recycling asymmetric hydrogenation catalysts by their immobilisation onto ion-exchange resins

被引:18
作者
Barbaro, P
Bianchini, C
Giambastiani, G
Oberhauser, W
Bonzi, LM
Rossic, F
Dal Santo, V
机构
[1] CNR, Ist Chim Composti Organo Met, Area Ric Firenze, I-50019 Florence, Italy
[2] Univ Florence, Dipartimento Biol Vegetale, I-50121 Florence, Italy
[3] CNR, Ist Genet Vegetale, Area Ric Firenze, I-50019 Florence, Italy
[4] CNR, Ist Sci & Tecnol Mol, I-20133 Milan, Italy
关键词
D O I
10.1039/b406179a
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
New systems based on cationic chiral phosphine-rhodium complexes anchored to a commercial cation-exchange gel-type resin showed high efficiency and easy recycling in the asymmetric hydrogenation of prochiral olefins.
引用
收藏
页码:1783 / 1784
页数:2
相关论文
共 31 条
[1]  
Anastas P. T., 1998, GREEN CHEM THEORY PR
[2]   A new technique for anchoring homogeneous catalysts [J].
Augustine, R ;
Tanielyan, S ;
Anderson, S ;
Yang, H .
CHEMICAL COMMUNICATIONS, 1999, (13) :1257-1258
[3]  
AUGUSTINE RL, 1998, C CHIR TECH
[4]   Recent aspects of asymmetric catalysis by immobilized chiral metal catalysts [J].
Bianchini, C ;
Barbaro, P .
TOPICS IN CATALYSIS, 2002, 19 (01) :17-32
[5]  
Bianchini C, 2001, ADV SYNTH CATAL, V343, P41, DOI 10.1002/1615-4169(20010129)343:1<41::AID-ADSC41>3.0.CO
[6]  
2-P
[7]   ENANTIOSELECTIVE SYNTHESIS USING CHIRAL HETEROGENEOUS CATALYSTS [J].
BLASER, HU .
TETRAHEDRON-ASYMMETRY, 1991, 2 (09) :843-866
[8]  
BLASER HU, 1995, CHIRAL REACTIONS HET
[9]  
Brown J. M., 1999, COMPREHENSIVE ASYMME, V1
[10]  
BROWN JM, 1980, CHEM COMMUN, P344