Rhenium-catalyzed amination of alcohols by hydrogen transfer process

被引：41

作者：

Abdukader, Ablimit ^{[1
,2
]}

Jin, Hongming ^{[1
]}

Cheng, Yixiang ^{[1
]}

Zhu, Chengjian ^{[1
]}

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Sch Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China

[2] Xinjiang Univ, Sch Chem & Chem Engn, Urumqi 830046, Peoples R China

来源：

TETRAHEDRON LETTERS | 2014年 / 55卷 / 30期

基金：

高等学校博士学科点专项科研基金; 中国国家自然科学基金;

关键词：

Alcohol; Hydrogen transfer; Rhenium; Homogeneous catalysis; Amination; N-HETEROCYCLIC CARBENE; C-H; DEHYDRATIVE ALKYLATION; SELECTIVE ALKYLATION; RECYCLABLE CATALYST; SECONDARY ALCOHOLS; COUPLING REACTIONS; IRIDIUM COMPLEX; PRIMARY AMINES; ACTIVATION;

D O I：

10.1016/j.tetlet.2014.05.068

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The rhenium heptahydride complex [ReH7(PCy3)(2)] was found to be an effective homogeneous catalyst for amination of various alcohols through hydrogen transfer mechanism. Under carbon monoxide atmosphere, a variety of primary and secondary alcohols could directly undergo the C-N coupling process. (C) 2014 Published by Elsevier Ltd.

引用

页码：4172 / 4174

页数：3

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