Rhenium-catalyzed amination of alcohols by hydrogen transfer process

被引：41
|
作者：
Abdukader, Ablimit [1 ,2 ]
Jin, Hongming [1 ]
Cheng, Yixiang [1 ]
Zhu, Chengjian [1 ]
机构：
[1] Nanjing Univ, State Key Lab Coordinat Chem, Sch Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China
[2] Xinjiang Univ, Sch Chem & Chem Engn, Urumqi 830046, Peoples R China
来源：
TETRAHEDRON LETTERS | 2014年 / 55卷 / 30期
基金：
中国国家自然科学基金; 高等学校博士学科点专项科研基金;
关键词：
Alcohol; Hydrogen transfer; Rhenium; Homogeneous catalysis; Amination; N-HETEROCYCLIC CARBENE; C-H; DEHYDRATIVE ALKYLATION; SELECTIVE ALKYLATION; RECYCLABLE CATALYST; SECONDARY ALCOHOLS; COUPLING REACTIONS; IRIDIUM COMPLEX; PRIMARY AMINES; ACTIVATION;
D O I：
10.1016/j.tetlet.2014.05.068
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The rhenium heptahydride complex [ReH7(PCy3)(2)] was found to be an effective homogeneous catalyst for amination of various alcohols through hydrogen transfer mechanism. Under carbon monoxide atmosphere, a variety of primary and secondary alcohols could directly undergo the C-N coupling process. (C) 2014 Published by Elsevier Ltd.
引用
收藏
页码：4172 / 4174
页数：3
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