Proton Conducting Copolymer Electrolytes Based on Vinyl Phosphonic Acid and 5-(Methacrylamido)tetrazole

被引：19

作者：

Sinirlioglu, Deniz ^{[1
]}

Celik, Sevim Unugur ^{[1
]}

Muftuoglu, Ali Ekrem ^{[2
]}

Bozkurt, Ayhan ^{[1
]}

机构：

[1] Fatih Univ, Dept Chem, TR-34500 Istanbul, Turkey

[2] Yildiz Tech Univ, Fac Chem & Met Engn, Dept Chem Engn, TR-34220 Esenler, Turkey

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 2014年 / 215卷 / 03期

关键词：

5-(methacrylamido)tetrazole; proton conductivity; vinyl phosphonic acid; VINYLPHOSPHONIC ACID; FUEL-CELL; POLYMER ELECTROLYTES; EXCHANGE MEMBRANES; POLY(VINYLPHOSPHONIC ACID); POLYBENZIMIDAZOLES; PBI; DEGRADATION; HYDROGEL;

D O I：

10.1002/macp.201300655

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Copolymer electrolytes based on 5-(methacrylamido)tetrazole (MTet) and vinyl phosphonic acid (VPA) are prepared. The obtained copolymers are analyzed by FTIR, H-1 NMR, C-13 NMR, and P-31 NMR spectroscopy, thermogravimetric analysis (TGA), differantial scanning calorimetry (DSC), energy dispersive X-ray spectrometry (EDS), elemental analysis (EA), cyclic voltammetry (CV), and impedance spectroscopy. The morphology of the copolymers is characterized by X-ray diffraction (XRD), atomic force microscopy (AFM) and scanning electron microscopy (SEM). The highest proton conductivity is obtained as 0.01 S/cm at 150 degrees C and in anhydrous conditions.

引用

收藏

页码：269 / 279

页数：11

相关论文

共 57 条

[1] Nanocomposite polymer electrolytes membranes based on Poly(vinylphosphonic acid)/SiO2 [J].

Aslan, Ayse ;

Golcuk, Kurtulus ;

Bozkurt, Ayhan .

JOURNAL OF POLYMER RESEARCH, 2012, 19 (12)

[2] Nanocomposite polymer electrolyte membranes based on poly (vinylphosphonic acid)/sulfated nano-titania [J].

Aslan, Ayse ;

Bozkurt, Ayhan .

JOURNAL OF POWER SOURCES, 2012, 217 :158-163

[3] Development and characterization of polymer electrolyte membranes based on ionical cross-linked poly(1-vinyl-1,2,4 triazole) and poly(vinylphosphonic acid) [J].

Aslan, Ayse ;

Bozkurt, Ayhan .

JOURNAL OF POWER SOURCES, 2009, 191 (02) :442-447

[4] Solid-State NMR Spectroscopic Studies of Propylphosphonic Acid Functionalized SBA-15 Mesoporous Silica: Characterization of Hydrogen-Bonding Interactions [J].

Bibent, Nicolas ;

Charpentier, Thibault ;

Devautour-Vinot, Sabine ;

Mehdi, Ahmad ;

Gaveau, Philippe ;

Henn, Franois ;

Silly, Gilles .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2013, (13) :2350-2361

[5] SOLID-STATE 2-DIMENSIONAL C-13-H-1 CORRELATION (HETCOR) NMR-SPECTRUM OF AMORPHOUS POLY(2,6-DIMETHYL-PARA-PHENYLENE OXIDE) (PPO) [J].

BIELECKI, A ;

BURUM, DP ;

RICE, DM ;

KARASZ, FE .

MACROMOLECULES, 1991, 24 (17) :4820-4822

[6] Synthesis, microstructure, and acidity of poly (vinylphosphonic acid) [J].

Bingol, Bahar ;

Meyer, Wolfgang H. ;

Wagner, Manfred ;

Wegner, Gerhard .

MACROMOLECULAR RAPID COMMUNICATIONS, 2006, 27 (20) :1719-1724

[7] Proton conducting copolymers on the basis of vinylphosphonic acid and 4-vinylimidazole [J].

Bozkurt, A ;

Meyer, WH ;

Gutmann, J ;

Wegner, G .

SOLID STATE IONICS, 2003, 164 (3-4) :169-176

[8] Proton conducting blends of poly(4-vinylimidazole) with phosphoric acid [J].

Bozkurt, A ;

Meyer, WH .

SOLID STATE IONICS, 2001, 138 (3-4) :259-265

[9] Anhydrous proton-conducting properties of triazole-phosphonic acid copolymers:: a combined study with MAS NMIR [J].

Celik, Sevim Ue ;

Akbey, Uemit ;

Graf, Robert ;

Bozkurt, Ayhan ;

Spiess, Hans W. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2008, 10 (39) :6058-6066

[10] Proton-conducting properties of acid-doped poly(glycidyl methacrylate)-1,2,4-triazole systems [J].

Celik, Sevim Uenueguer ;

Akbey, Uemit ;

Bozkurt, Ayhan ;

Graf, Robert ;

Spiess, Hans W. .

MACROMOLECULAR CHEMISTRY AND PHYSICS, 2008, 209 (06) :593-603

← 1 2 3 4 5 6 →